Highly concentrated aqueous solutions of...

Compositions – Compositions containing a single chemical reactant or plural... – Organic reactant

Reexamination Certificate

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C562S554000, C562S575000

Reexamination Certificate

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07056450

ABSTRACT:
An aqueous high-concentration solution of N,N-dialkylglycine, economical, easy to handle, and useful for subsequent organic chemical reactions, is provided. Also is provided a process for production thereof. The aqueous high-concentration solution of N,N-dialkylglycine which contains the N,N-dialkylglycine at a concentration of 30–80% by mass, and a metal-mineral acid salt at a content of 0.3–3% by mass can be produced industrially from an aqueous N,N-dialkylglycine alkali metal salt as the source material by the steps of(i) neutralizing an aqueous solution of an N,N-dialkylglycine alkali metal salt with a mineral acid,(ii) condensing the obtained aqueous solution by removal of water, and(iii) separating by solid-liquid separation the deposited alkali metal-mineral acid salt from the resulting slurry of the aqueous N,N-dialkylglycine solution and the alkali metal-mineral acid salt.

REFERENCES:
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patent: 4968839 (1990-11-01), Noell
patent: 6875890 (2005-04-01), Zhang
patent: 292 239 (1991-07-01), None
patent: 58-34478 (1983-07-01), None
patent: 63-101351 (1988-05-01), None
patent: 2003176261 (2003-06-01), None
Derwent ACC-No.: 1991-369787, patent DD 292239A, pub Jul. 25, 1991, Dietze et al.
JPO machine translation of JP 2003176261 A (Jun. 24, 2003) Ueda et al.
Pahal, S. et al. “An Anomalous Eschweiler-Clarke Reaction”, Tetrahedron Letters, 1991, vol. 32, No. 31, pp. 3847 to 3848.
Kagaku Daijiten Henshu Iinkai, Kagaku Daijiten 4, reduced-size edtion, Kyoritsu Shuppan Co., Ltd., Oct. 15, 1963, pp. 86, 87, 516, and 517.

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