Chemistry of inorganic compounds – Silicon or compound thereof – Oxygen containing
Patent
1975-07-10
1977-07-19
Stern, Edward
Chemistry of inorganic compounds
Silicon or compound thereof
Oxygen containing
423335, C01B 3316, C01B 3318
Patent
active
040369331
ABSTRACT:
A highly active superdry silica aerogel free of adsorbed water and hydrogen-bonded silanol groups the infrared spectrum of which is characterized by a single narrow intense band at about 3700 cm.sup..sup.-1 within the range between 4000 and 2000 cm.sup..sup.-1 indicating the presence of free silanol groups and which spectrum is further characterized by the absence of bonds indicating the presence of adsorbed water and hydrogen-bonded silanol groups, the said silica aerogel having been produced by subjecting a pyrolytically produced silica aerogel containing adsorbed water and both free and hydrogen-bonded silanol groups to treatment in a fluidized bed at a temperature between about 700.degree. and 1000.degree. C and at a pressure between 2 torrs and atmospheric pressure for a period between 1 second and a few minutes through which fluidized bed a stream of a dried gas that had been preheated to a temperature between 100.degree. and 300.degree. C was passed.
REFERENCES:
patent: 2660564 (1953-11-01), Davis
patent: 3053627 (1962-09-01), Flemmert
patent: 3148026 (1964-09-01), Roderburg et al.
patent: 3269799 (1966-08-01), Gunn, Jr.
patent: 3367742 (1968-02-01), Marotta et al.
patent: 3645684 (1972-02-01), De Cuir
patent: 3859420 (1975-01-01), Laufer et al.
Book, "The Colloid Chem. of Silica and Silicates", by Ralph K. Iler, 1955 Ed., pp. 152, 153, Cornell Univ. Press, N. Y.
Laufer Siegmar
Roy Waldemar
Deutsche Gold- und Silber-Scheideanstalt vormals Roessler
Stern Edward
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