High unsaturation butyl rubbers with additives

Chemistry of carbon compounds – Miscellaneous organic carbon compounds

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260 318DR, 260 336AQ, 260 4247, 525333, C08C 1930, C08J 324, C08K 536

Patent

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042293251

ABSTRACT:
Substantially gel-free, high unsaturation copolymers of isobutylene and isoprene and high unsaturation terpolymers of isobutylene, isoprene and cyclopentadiene having a number average molecular weight of at least about 90,000 and a mole percent of unsaturation of at least 5% and the process for preparing said polymers which comprises carrying out the polymerization in a homogeneous phase, introducing to the system either an aluminum halide in a soluble form or a hydrocarbylaluminum dihalide and carrying the reaction out at a temperature of less than about -100.degree. C. Vulcanizable compositions are formed from the co- and ter- polymers by reacting them with a vulcanizing amount of sulfur donor and a delayed action accelerator, wherein the vulcanized compositions can be extended with fillers, non-polar process oils and rubbers.

REFERENCES:
patent: 2521359 (1950-09-01), Garber
patent: 3080337 (1963-03-01), Minckler et al.
patent: 3808177 (1974-04-01), Thaler et al.
patent: 3928297 (1975-12-01), Thaler et al.

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