High temperature total NO x sensor

Chemistry: electrical and wave energy – Apparatus – Electrolytic

Reexamination Certificate

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C204S412000, C204S429000, C205S781000, C205S780500

Reexamination Certificate

active

07611613

ABSTRACT:
A total NOxsensor with minimal interferences from CO and O2includes a yttria-stabilized zirconia (YSZ) pellet and a Pt-loaded zeolite Y layer. Furthermore, three platinum wires are attached to the YSZ surface which operate as the working, counter and reference electrode. A potentiostat is connected to the electrodes to maintain a fixed potential between the reference and working electrode. The potentiostat then monitors the relationship between time and current through the counter electrode.

REFERENCES:
patent: 5403452 (1995-04-01), Hielscher et al.
patent: 5667652 (1997-09-01), Liu et al.
patent: 6764591 (2004-07-01), Dutta et al.
Ono, M. et al., Solid State Ionics, 583, pp. 136-137, 2000.
Szabo, N.F. et al., “Microporous zeolite modified yttria stabilized zirconia &YSZ) sensors for nitric oxide (NO) determination in harsh environments”, Sensors and Actuators B: Chemical, vol. 82, No. 2, Feb. 28, 2002, pp. 142-149.
Adler S.B., “Factors Governing Oxygen Reduction in Solid Oxide Fuel Cell Cathodes”, Chem Rev. 104, pp. 4791-4843, 2004.
Bay, L. et al., “Dynamics of the YSZ-Pt interface”, Solid State Ionics 93, pp. 201-206, 1997.
Bjorefors, F. et al., “Electrochemical Detection Based on Redox Cycling Using Interdigitated Microarray Electrodes at μL/min Flow Rates”, Electroanalysis, 12, No. 4, pp. 255-261, 2000.
Brosha, E.L. et al., “Mixed potential sensors using lanthanum manganate and terbium yttrium zirconium oxide electrodes”, Sensors and Actuators B 87, pp. 47-57, 2002.
Bruser, V. et al., “Nox-Determination with Galvanic Zirconia Solid Electrolyte Cells”, Solid State Phenomena vols. 39-40, pp. 269-272, 1994.
Cabot, A. et al., “Mesoporous catalytic filters for semiconductor gas sensors”, Thin Solid Films, 436, pp. 64-69, 2003.
Coillard, V. et al., “Nitrogen monoxide detection with a planar spinel coated amperometric sensor”, Sensors and Actuators B 78, pp. 113-118, 2001.
Docquier, N. et al., “Combusstion control and sensors: a review”, Progress in Energy and Combusion Science 28, pp. 107-150, 2002.
Fleischer, M. et al., “Selective gas detection with high-temperature operated metal oxides using catalytic filters”, Sensors and Actuators B 69, pp. 205-210, 2000.
Garzon, F.H. et al., “Solid-state mixed potential gas sensors: theory, experiments and challenges”, Solid State Ionics, 136-137, pp. 633-638, 2000.
Gopel, W. et al., “Trends in the development of solid state amperometric and potentiometric high temperature sensors”, Solid State Ionics, 136-137, pp. 519-531, 2000.
Gur, T.M. et al., “Importance of electrode/zirconia interface morphology in high-temperature solid electrolyte cells”, J. of Applied Electrochemistry, 17, pp. 800-806, 1987.
Hua, L. et al, “Amperometric Detection of Carbohydrates by Capillary Electrophoresis with a Cuprous Oxide Modified Sol-Gel Carbon Composite Electrode”, Electroanalysis, 12, No. 4, pp. 287-291, 2000.
Hubalek, J. et al., “Pt-loaded Al2O3 catalytic filters for screen-printed WO3 sensors highly selective to benzene”, Sensors and Actuators B 101, pp. 277-283, 2004.
Hugon, O. et al., “Gas separation with a zeolite filter, application to the selectivity enhancement of chemical sensors”, Sensors and Actuators B 67, pp. 235-243, 2000.
Kammer, K., “Electrochemical DeNOx in solid electrolyte cells-an overview”, Applied Catalysis B: Environmental 58, pp. 33-39, 2005.
Kato, T. et al., “Influence of cell configuration on measuring interfacial impedances between a solid electrolyte and an electrode”, Solid State Ionics 132, pp. 287-295, 2000.
Kitsukawa, S. et al., “The interference elimination for gas sensor by catalyst filters”, Sensors and Actuators B 65, pp. 120-121, 2000.
Magori, E. et al., “Thick film device for the detection of NO and oxygen in exhaust gases”, Sensors and Actuators B95, pp. 162-169, 2003.
Miura, N. et al., “Selective detection of NO by using an amperometric sensor based on stabilized zirconia and oxide electrode”, Solid State Ionics, 117, pp. 283-290, 1999.
Miura, N. et al., “Progress in mixed-potential type devices based on solid electrolyte for sensing redox gases”, Solid State Ionics, 136-137, pp. 533-542, 2000.
Miura, N. et al., “Stabilized zirconia-based sensor using oxide electrode for detection of NOx in high-temperature combustion-exhausts”, Solid State Ionics, 86-88, pp. 1069-1073, 1996.
Miura, N. et al., “High-temperature potentiometric/amperometric NOx sensors combining stabilized zirconia with mixed-metal oxide electrode”, Sensors and Actuators B 52, pp. 169-178, 1998.
Menil, F. et al., “Critical review of nitrogen monoxide sensors for exhause gases of lean burn engines”, Sensors and Actuators B 67, pp. 1-23, 2000.
Ono, M. et al., “Amperometric sensor based on NASICON and NO oxidation catalysts for detection of total NOx in atmospheric environment”, Solid State Ionics, 136-137, pp. 583-588, 2000.
Ono, T. et al., “Performance of the NOx sensor based on mixed potential for automobiles in exhaust gases”, JSAE Review, 22, pp. 49-55, 2001.
Reinhardt, G. et al., “Sensing small molecules with amperometric sensors”, Solid State Ionics, 150, pp. 79-92, 2002.
Schwandt, C. et al., “Variation of the oxygen exhange rate of zirconia-based electrodes by electrochemical pretreatment”, Solid State Ionics, 112, pp. 229-236, 1998.
Skelton, D.C. et al., “A surface-science-based model for the selectivity of platinum-gold alloy electrodes in zirconia-based NOx sensors”, Sensors and Actuators B 96, pp. 46-52, 2003.
Sridhar, S. et al., “Transient and Permanent Effects of Direct Current on Oxygen Transfer across YSZ-Electrode Interfaces”, J. Electrochem. Soc. vol. 144, No. 7, pp. 2479-2485, Jul. 1997.
Szabo, N.F. et al., “Strategies for total NOx measurement with minimal CO interference utilizing a microporous seolitic catalytic filter”, Sensors and Actuators B 88, pp. 168-177, 2003.
Trimboli, J. et al., “Oxidation chemistry and electrical activity of Pt on titania: development of a novel zeolite-filter hydrocarbon sensor”, Sensors and Actuators B 102, pp. 132-141, 2004.
Walsh, K.J. et al., “Nitric oxide reduction using platinum electrodes on yttria-stabilized zirconia”, Solid State Ionics, 93, pp. 17-31, 1997.
Wang, J. et al., “Enhanced Stability of Glassy Carbon Detectors following a Simple Electrochemical Pretreatment”, Anal. Chem., 58, pp. 1787-1790, 1986.
Warburton, P.R. et al., “Amperometric Gas Sensor Response Times”, Anal. Chem, 70, pp. 998-1006, 1998.
Schmidt-Zhang, P. et al., “A novel thick film sensor for simultaneous O2 and NO monitoring in exhaust gases”, Sensors and Actuators, B 70, pp. 25-29, 2000.
de Graaf, J. et al., “Preparation of Highly Dispersed Pt Particles in Zeolite Y with a Narrow Particle Size Distribution: Characterization by Hydrogen Chemisorption, TEM, EXAFS Spectroscopy, and Particle Modeling”, J. of Catalysis, 203, pp. 307-321, 2001.
Fritz, A. et al., “The current state of research on automotive lean NOx catalysis”, Applied Catalysis B: Environmental 13, pp. 1-25, 1997.
Lu, G. et al., “High-temperature sensors for NO and NO2 based on stabilized zirconia and spinel-type oxide electrodes”, J. Mater. Chem. 7 (8), pp. 1445-1449, 1997.
Yang, J.C. et al. “High temperature amperometric total NOx sensors with platinum-loaded zeolite Y electrodes”, Science Direct, Sensors and Actuators B 123, pp. 929-936, 2007, available on-line Dec. 4, 2006.

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