High temperature polymerization process using ionic catalysts to

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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526127, 526131, 526160, 526170, 5263486, 526352, 502155, C08F 4643

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054080177

ABSTRACT:
This invention relates to a process for polymerizing olefins at high pressures in a polymerization medium at high temperature utilizing an ionic olefin polymerization catalyst derived from the reaction of a cyclopentadienyl-containing transition metal compound having a hydrolyzable alkyl or hydride ligand with an ion exchange activator. The ionic catalyst system has been found to be highly active at temperatures of 160.degree. C. or greater, to provide a process capable of producing polymer products of desired chemical and physical properties at high production rates.

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