High sulfur level plastic container sulfonation process and arti

Coating processes – Interior of hollow article coating – Coating by vapor – gas – mist – or smoke

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Details

264 83, 264340, 427223, 425 74, B05D 722

Patent

active

052021610

ABSTRACT:
A process for treating a container comprised of a normally solid, polymer surface with a sulfur-containing compound is carried out by contacting the surface at a temperature of about 120.degree. to about 140.degree. F. with a sulfur-containing compound. Subsequently, the surface is contacted with a neutralizing agent. The process is conducted for a such a period of time and with such concentrations of the sulfur-containing compound and the neutralizing agent that the container has average permeability to unleaded gasoline having octane number of 93 of not greater than about 0.021 g/hr.
The surface, after the treatment, comprises about 700 to about 1800 micrograms of sulfur per square inch of the surface and it is penetrated by the sulfur-containing compound to an average depth of at least about 15 microns.

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