High-strength steel plate having high dynamic deformation...

Metal treatment – Stock – Ferrous

Reexamination Certificate

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C148S320000, C148S544000, C148S545000, C148S546000, C148S547000, C148S548000

Reexamination Certificate

active

06319338

ABSTRACT:

TECHNICAL FIELD
The present invention relates to high strength hot rolled and high strength cold rolled steel sheets having high flow stress during dynamic deformation, which can be used for automotive members and the like to provide assurance of safety for passengers by efficiently absorbing the impact energy of a collision, as well as a method for producing the same.
BACKGROUND ART
In recent years, protection of passengers from automobile collisions has been acknowledged as an aspect of utmost importance for automobiles, and hopes are increasing for suitable materials exhibiting excellent high-speed deformation resistance. For example, by applying such materials to front side members of automobiles, the energy of frontal collisions may be absorbed as the materials are crushed, thus alleviating the impact on passengers.
Since the strain rate for deformation undergone by each section of an automobile upon collision reaches about 10
3
(l/s), consideration of the impact absorption performance of a material requires knowledge of its dynamic deformation properties in a high strain rate range. Because it is also essential to consider at the same time such factors as energy savings and CO
2
exhaust reduction, as well as weight reduction of the automobile, requirements for effective high-strength steel sheets are therefore increasing.
For example, in CAMP-ISIJ Vol. 9 (1996), pp.1112-1115 the present inventors have reported on the high-speed deformation properties and impact energy absorption of high-strength thin steel sheets, and in that article it was reported that the dynamic strength in the high strain rate range of about 10
3
(l/s) is drastically increased in comparison to the static strength in the low strain rate of 10
−3
(l/s), that the strain rate dependence for deformation resistance varies based on the strengthening mechanism for the material, and that TRIP (transformation induced plasticity) steel sheets and DP (ferrite/martensite dual phase) steel sheets possess both excellent formability and impact absorption properties compared to other high strength steel sheets.
Furthermore, Japanese Unexamined Patent Publication No. 7-18372, which provides retained austenite-containing high strength steel sheets with excellent impact resistance and a method for their production, discloses a solution for impact absorption simply by increasing the yield stress brought about by a higher deformation rate; however, it has not been demonstrated what other aspects of the retained austenite should be controlled, apart from the amount of retained austenite, in order to improve impact absorption.
Thus, although understanding continues to improve with regard to the dynamic deformation properties of member constituent materials affecting absorption of impact energy in automobile collisions, it is still not fully understood what properties should be maximized to obtain steel materials for automotive members with more excellent impact energy absorption properties, and on what criteria the selection of materials should be based. Steel materials for automotive members are formed into the required part shapes by press molding and, after usually undergoing painting and baking, are then incorporated into automobiles and subjected to actual instances of impact. However, it is still not clear what steel-strengthening mechanisms are suitable for improving the impact energy absorption of steel materials against collisions subsequent to such pre-deformation and baking treatment.
DISCLOSURE OF THE INVENTION
It is an object of the present invention to provide high-strength steel sheets with high impact energy absorption properties as steel materials for shaping and working into such parts as front side members which absorb impact energy upon collision, as well as a method for their production. First, the high-strength steel sheets exhibiting high impact energy absorption properties according to the present invention include:
(1) high-strength steel sheets with high flow stress during dynamic deformation, characterized in that the microstructure of the steel sheets in their final form is a composite microstructure of a mixture of ferrite and/or bainite, either of which is the dominant phase, and a third phase including retained austenite at a volume fraction between 3% and 50%, wherein the average value &sgr;dyn (MPa) of the flow stress in the range of 3~10% of equivalent strain when deformed in a strain rate range of 5×10
2
~5×10
3
(l/s) after pre-deformation of greater than 0% and less than or equal to 10% of equivalent strain, satisfies the inequality: &sgr;dyn≧0.766×TS+250 as expressed in terms of the maximum stress TS (MPa) in the static tensile test as measured in a strain rate range of 5×10
−4
~5×10
−3
(l/s) without pre-deformation, and the work hardening coefficient between 1% and 5% of strain is at least 0.080; and
(2) high-strength steel sheets with high flow stress during dynamic deformation according to (1) above, wherein the value of the work hardening coefficient between 1% and 5% of strain x yield strength is at least 40.
They further include:
(3) high-strength steel sheets with high flow stress during dynamic deformation, where the microstructure of the steel sheets in their final form is a composite microstructure of a mixture of ferrite and/or bainite, either of which is the dominant phase, and a third phase including retained austenite at a volume fraction between 3% and 50%, wherein the average value &sgr;dyn (MPa) of the flow stress in the range of 3~10% of equivalent strain when deformed in a strain rate range of 5×10
2
~5×10
3
(l/s) after pre-deformation of greater than 0% and less than or equal to 10% of equivalent strain, satisfies the inequality: &sgr;dyn≧0.766×TS+250 as expressed in terms of the maximum stress TS (MPa) in the static tensile test as measured at a strain rate range of 5×10
−4
~5×10−3 (l/s) without pre-deformation, the value (M) determined by the solid solution [C] in the retained austenite and the average Mn equivalents of the steel {Mn eq=Mn+(Ni+Cr+Cu+Mo)/2}, defined by the equation M=678−428×[C]−33 Mn eq is at least 70 and no greater than 250, the difference between the retained austenite volume fraction without pre-deformation and the retained austenite volume fraction after applying a pre-deformation of 5% of equivalent strain is at least 30% of the retained austenite volume fraction without pre-deformation, the work hardening coefficient between 1% and 5% of strain is at least 0.080, the mean grain diameter of the retained austenite is no greater than 5 &mgr;m; the ratio of the mean grain diameter of the retained austenite and the mean grain diameter of the ferrite or bainite in the dominant phase is no greater than 0.6 while the average grain diameter of the dominant phase is no greater than 10 &mgr;m and preferably no greater than 6 &mgr;m; the volume of the martensite is 3~30% while the mean grain diameter of the martensite is no greater than 10 &mgr;m and preferably no greater than 5 &mgr;m, the volume fraction of the ferrite is at least 40%, the yield ratio is no greater than 85%, and the value of the tensile strength×total elongation is at least 20,000.
(4) The high-strength steel sheets of the present invention are also high-strength steel sheets containing, in terms of weight percentage, C at from 0.03% to 0.3%, either or both Si and Al at a total of from 0.5% to 3.0% and if necessary one or more from among Mn, Ni, Cr, Cu and Mo at a total of from 0.5% to 3.5%, with the remainder Fe as the primary component, or they are high-strength steel sheets with high flow stress during dynamic deformation obtained by further addition, if necessary, to the aforementioned high-strength steel sheets, or one or more from among Nb, Ti, V, P. B, Ca and REM, with one or more from among Nb, Ti and V at a total of no greater than 0.3%, P at no greater than 0.3%, B at no greate

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