High strength high toughness TiB.sub.2 ceramics

Compositions: ceramic – Ceramic compositions – Carbide or oxycarbide containing

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501 88, 501 89, 501 87, 501 91, 501 96, C04B 3556, C04B 3558

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active

049333089

ABSTRACT:
A ceramic sintered body comprising TiB.sub.2 as the principal component, 0.5 to 30 wt. % of SiC and 2 to 40 wt. % of ZrO.sub.2. In some cases ZrO.sub.2 includes stabilizers for tetragonal crystal, such as Y.sub.2 O.sub.3, MgO or CeO.sub.2. The sintered body has a dense structure where TiB.sub.2, ZrO.sub.2 and SiC uniformly disperse. ZrO.sub.2 is located at the grain boundary of TiB.sub.2, and inhibits the grain growth of TiB.sub.2 as well as improves the strength of the sintered body by binding it to TiB.sub.2 strongly. SiC is located not only at the grain boundary but also on the inside of both grains. Since the contract of SiC during cooling process of the sintered body is less than TiB.sub.2 and ZrO.sub.2, compressive stress is produced in SiC and around thereof. The sintered body is remarkably strengthened by the residual compressive stress, and simultaneously, the high fracture toughness is also achieved.

REFERENCES:
patent: 4555358 (1985-11-01), Matsushita et al.
patent: 4762810 (1988-08-01), Endo et al.
patent: 4837231 (1989-06-01), Endo et al.

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