High-strength beryllium-free moulded body made from...

Metal treatment – Stock – Amorphous – i.e. – glassy

Reexamination Certificate

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C148S421000

Reexamination Certificate

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10487383

ABSTRACT:
High-strength, beryllium-free moulded bodies made from zirconium alloys which may be plastically deformed comprise a material essentially corresponding to the following formula in composition: Zra(E1)b(E2)c(E3)d(E4)e, where E1=one or several of Nb, Ta, Mo, Cr, W, Ti, V, Hf and Y, E2=one or several of Cu, Au, Ag, Pd and Pt, E3=one or several of Ni, Co, Fe, Zn and Mn, E4=one or several of AI, Ga, Si, P, C, B, Sn, Pb and Sb, a=100−(b+c+d+e), b=5 to 15, c=5 to 15, d=0 to 15 and e=5 to 15 (a, b, c, d, e in atom %). The moulded body essentially comprises a homogeneous, microstructural structure which is a glass-like or nano-crystalline matrix with a ductile, dendritic, cubic body-centered phase embedded therein.

REFERENCES:
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patent: 6692590 (2004-02-01), Xing et al.
patent: 6918973 (2005-07-01), Hufnagel et al.
patent: 2002/0003013 (2002-01-01), Hays
patent: 198 33 329 (2000-01-01), None
patent: WO-00/68469 (2000-11-01), None
Kuhn, U. et al., “ZrNbCuNiAl bulk metallic glass matrix composites containing dendritic bcc precipitates”, Applied Physics Letters, vol. 40, No. 14, Apr. 8, 2002, pp. 2478-2480.
Greer, A.L., “From Metallic Glasses to Nanocrystalline Solids”, Proceedings of the 22ndRiso International Symposium on Materials Science, Riso National Laboratory, Roskilde, Denmark, 2001, pp. 461-481.
Kuehn U et al: “As-Cast Quasicrystalline Phase in a Zr-Based Multicomponent Bulk Alloy” Applied Physics Letters, American Institute of Physics. New York, US, vol. 77, No. 20, Nov. 13, 2000, pp. 3176, paragraphs 2, 3: figure 1, p. 3177, col. 2, line 26-line 29.
C. C. Hays, C. P. Kim, W. L. Johnson: “Improved mechanical behaviour of bulk metallic glasses containing in situ formed ductile phase dendrite dispersions” Materials Science and Engineering, May 31, 2001, pp. 650-655, XP00222028, the whole document.
Loeffler J F et al: “Crystallization of Bulk Amorphous Zr-Ti(Nb)-Cu-Ni-Al” Applied Physics Letters, American Institute of Physics, New York, US, vol. 77, No. 4, Jul. 24, 2000, pp. 525-527, XP000954870, ISSN: 0003-6951, the whole document.
Cang Fan, Chunfei Li, Akihisa Inoue: “Nanocrystal composites in Zr-Nb-Cu-Al metallic glasses” Journal of Non-Crystaline Solids, 2000, pp. 28-33, XP002222029, the whole document.

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