High speed pickling with recycling of acid

Details High speed pickling with recycling of acid High speed pickling with recycling of acid

2001-04-11

2003-04-22

Gulakowski, Randy (Department: 1746)

Cleaning and liquid contact with solids

Processes

Longitudinally traveling work of bar, strip, strand, sheet...

Reexamination Certificate

active

06551413

ABSTRACT:

TECHNICAL FIELD
This invention relates to treating steel, particularly to the pickling of steel, and more particularly to the control of the pickling bath used for pickling steel strip moving at high speeds.
BACKGROUND OF THE INVENTION
In the past ten to fifteen years there has been considerable evolution in the pickling of steel. The art has progressed from simple dip tanks to horizontal pickling tanks and on to the extremely advanced turboflow systems, which led to the generation of more ecological and economical processes, all the while improving the quality of the treatment that the material had to undergo. Nevertheless, virtually all of the newer treatment facilities (primarily steel strip picking plants) were designed for hot strips with thicknesses ranging from 1.8 to 6 millimeters. Average strip thickness throughout the world is about 3 millimeters.
Today, thanks to the hot rolling technology combined with the thin slab casting technology, the hot strip sector produces thicknesses as low as 0.7 millimeters while retaining the ability to handle 6 mm in thickness. In order to produce substantially thinner hot strips in the plants, the strip must run at higher speeds during treatment. For example, with a production of 1.5 million tons per year and a 3 mm thick reference strip, strip speed is 250 meters per minute. With a 1.5 mm thick strip, processing speed at the same production capacity is 500 meters per minute; 400 meters per minute is to be expected for strip 2.4 mm thick at the same production rate.
Pickling technologies currently available on the market are generally not compatible with such high speeds, since the facility is usually designed to propel the strip through a horizontal pickling plant under low tension. This presents guiding problems, and the added condition of high speed of the strip causes the strip to carry the pickling liquid on its surface. If the strip is propelled horizontally into the acid bath with considerable kinetics, the quantity of liquid carried away may be so great that adequate pickling and safe operation are difficult to guarantee. A boundary layer of acid tends to remain stationary with respect to the strip, resulting in poor contact efficiency.
In the past, pickling tanks and their covers have been constructed to control acid vapors, as in U.S. Pat. Nos. 3,803,996 and 3,648,593 to Marshall and U.S. Pat. No. 4,592,784 to Ghizzi. Weirs have been used to create cascades of acid from one tank or zone to the next. See Hampel U.S. Pat. No. 3,473,962 and Matiussi U.S. Pat. No. 5,179,967. Acid has been collected in separate vessels for recycling, as in Galloway U.S. Pat. No. 4,007,750 and Gravert et al U.S. Pat. No. 5,853,495; note also Zednicek et al U.S. Pat. No. 5,716,455, which discloses restrictions constructed to shear the acid on the strip, causing turbulence; the acid is recycled through drains. In pickling wire, Hone et al in U.S. Pat. Nos. 4,950,333 and 4,951,694 utilize the dynamics of the process by generating waves of acid, which are controlled by weirs.
Acid is recycled from a high end of an acid tank to a low end by gravity through a pipe, as configured by Lordo in U.S. Pat. No. 5,803,981. Kimura et al, in U.S. Pat. No. 5,116,447, recycles “wakes” of acid stripped by weir members shaped to direct the excess acid to the sides of the weirs for draining.
As indicated above, the kinetics of the extremely high speed of the newer pickling lines results in rapid movement of the acid in the bath, particularly that above the strip, towards the downstream end of the process and apparatus. This causes increasing depths of acid in the downstream ends of the pickling vessels, compounding the hazards for workers and causing environmental problems due to the possibility of acid escaping from the apparatus, and economic loss from the underuse of the acid.
SUMMARY OF THE INVENTION
Our invention makes possible the efficient pickling of strip steel moving at high speeds while conserving acid and providing improved ecological and economic benefits. It is applicable not only for high speed pickling, but also for other high-speed strip treatment, such as rinsing and cleaning.
Our invention comprises a pickling apparatus for pickling steel strip traveling at high speed substantially horizontally, including a plurality of acid-containing sections in series for contacting said strip with acid, each of said acid-containing sections comprising an upstream end and a downstream end, comprising (a) means for maintaining a desired level of strip therein while permitting acid to flow on the bottom as well as the top thereof, (b) an exit for the strip in the downstream end including an arcuate deflector for acid flowing with the strip and on top thereof, the arcuate deflector being shaped so as to scoop the flowing acid and reverse its direction of flow at a level higher than that of the acid on the strip, and (c) an inclined separator panel for receiving acid from the deflector in the reverse direction of flow and guiding it downwardly to the upstream end of the section.
Below the deflector, we place a constriction on the flow of acid on top of the strip, followed by a divergent zone. The constriction, combined with the divergent zone, accelerates the flow of the acid remaining on top of the strip so that it is no longer merely carried by the strip. The constriction also aids the function of the deflector by urging the higher levels of acid upwardly towards the deflector so they can be recirculated.
Our invention optionally includes the use of a special cover for the pickling tanks and other optional features and variations, as will be seen below.


REFERENCES:
patent: 3473962 (1969-10-01), Hampel
patent: 3625232 (1971-12-01), Speelmanns
patent: 3648593 (1972-03-01), Marshall
patent: 3803996 (1974-04-01), Marshall
patent: 4007750 (1977-02-01), Galloway
patent: 4592784 (1986-06-01), Ghizzi
patent: 4950333 (1990-08-01), Hone et al.
patent: 4951694 (1990-08-01), Hone et al.
patent: 4996998 (1991-03-01), Seiz et al.
patent: 5116447 (1992-05-01), Kimura et al.
patent: 5179967 (1993-01-01), Mattiussi
patent: 5716455 (1998-02-01), Zednicek et al.
patent: 5803981 (1998-09-01), Lordo
patent: 5853495 (1998-12-01), Gravert et al.
patent: 6016819 (2000-01-01), Murray et al.
patent: 6260563 (2001-07-01), Lordo et al.
patent: 0 795 629 (1997-09-01), None

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