Chemistry: electrical current producing apparatus – product – and – Current producing cell – elements – subcombinations and... – Separator – retainer or spacer insulating structure
Reexamination Certificate
2001-07-26
2003-12-02
Tsang-Foster, Susy (Department: 1745)
Chemistry: electrical current producing apparatus, product, and
Current producing cell, elements, subcombinations and...
Separator, retainer or spacer insulating structure
C429S165000
Reexamination Certificate
active
06656629
ABSTRACT:
BACKGROUND OF THE INVENTION
The present invention generally relates to an electrochemical cell and, more particularly, relates to a high rate capable electrochemical cell having an increased anode-to-cathode interface surface area.
Electrochemical cells are commonly employed to supply voltage for electrically operated devices, and particularly for portable electrically operated devices. Currently, the popular alkaline cells of the generally cylindrical type are commercially available in industry standard sizes including D-, C-, AA-, AAA-, and AAAA-size cells, as well as other sizes and configurations. Electrochemical cells, such as the aforementioned type, commonly provide a predetermined open circuit voltage supply.
Conventional cylindrical alkaline cells generally have a cylindrical-shaped steel can provided with a positive cover at one end and a negative cover at the opposite end. The cylindrical cell has a positive electrode, commonly referred to as the cathode, which is often formed of a mixture of manganese dioxide, graphite, potassium hydroxide solution, deionized water, and a TEFLON® solution formed about the interior side surface of the cylindrical steel can. A cup-shaped separator is generally centrally disposed in an inner cylindrical volume of the can about the interior surface of the cathode. A negative electrode, commonly referred to as the anode, is typically formed of zinc powder, a gelling agent, and other additives, and is disposed within the separator. An electrolyte solution is also disposed in the can. One example of a conventional cylindrical cell is disclosed in U.S. Pat. No. 5,501,924, which is hereby incorporated by reference.
Conventional cells of the aforementioned cylindrical type commonly have a single anode and a single cathode contained within the steel can, with the separator interfaced between the two electrodes. With the bobbin type cell construction, the cathode is disposed adjacent the inner wall of the steel can, while the anode is disposed within a cylindrical volume centrally formed in the cathode. Accordingly, the separator has an anode-to-cathode interface surface area generally defined by the shape and size of the anode and the cathode. With the conventional bobbin type cell, the anode-to-cathode interface surface area is approximately equal to the surface defining the periphery of the cylindrical anode.
Another cell construction, commonly referred to as the jelly-roll cell construction, employs a sheet of anode and a sheet of cathode tightly wound together with a separator interdisposed between the two electrode sheets. While conventional jelly-roll wound cells offer high rate capability with a large anode-to-cathode interface area, such cells have inherent limitations. For instance, the process of forming jelly-roll cells is time consuming and relatively expensive. Further, the jelly-roll separator consumes a relatively large amount of available volume, thereby compromising the volume that remains for active cell materials.
A primary goal in designing alkaline cells is to increase the service performance which is the length of time for the cell to discharge under a given load to a specific voltage at which the cell is no longer useful for its intended purpose. Commercially available alkaline cells have an external size that is defined by industry standards, thereby limiting the ability to increase the amount of active materials that can be utilized. Conventional approaches for improving high rate performance have focused on increasing the efficiency of the internal cell materials. The need for high rate capable cells is becoming even more important with the increasing demand from consumers using high tech, high drain electronics devices. To meet this demand, the need to find ways to increase high rate service performance remains a primary goal of the cell designers.
SUMMARY OF THE INVENTION
The present invention improves the high rate performance of an electrochemical cell by providing an easy-to-manufacture cell construction having an enhanced anode-to-cathode interfacial surface area to realize improved high rate service performance. To achieve this and other advantages, and in accordance with the purpose of the invention as embodied and described herein, the present invention provides an electrochemical cell including a container, a first electrode, and a second electrode. In addition, the cell further has an outer electrochemically active layer formed around the first electrode and separated therefrom by a separator. The first electrode and the second electrode are disposed in the container and separated from each other via a separator. The outer electrochemically active layer is in electrical contact with the second electrode, and a current collector is disposed in contact with the second electrode.
According to the assembly method of the present invention, a first electrode is formed having a conductive grid current collector integrally embedded therein. An outer separator covers the outer surface of the first electrode. An outer electrochemically active layer is disposed on top of the outer separator, and therefore wraps around the outside of the first electrode. The first electrode, outer electrochemically active layer and separator are disposed as a bobbin assembly into a container having a closed bottom end and an open top end. An inner separator is disposed in an inner cylindrical volume in the first electrode. A second electrode is disposed in the inner cylindrical volume of the first electrode and against the inner separator. A current collector is disposed in contact with the second electrode and the outer electrochemically active layer. A cover assembly is assembled to the open end of the container.
These and other features, advantages and objects of the present invention will be further understood and appreciated by those skilled in the art by reference to the following specification, claims and appended drawings.
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Batteries: Manganese Dioxideedited by Karl V. Kordesch, vol. 1, Union Carbide Corporation, Battery Products Division, Research Laboratory, Parma, Ohio, Marcel Dekker, Inc., New York 1974, p. 272, Title page, book cover. No month.
Eveready Battery Company Inc.
Fraser Stewart A.
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