Electric lamp and discharge devices: systems – Discharge device load – Plural gases or vapors in the discharge device
Reexamination Certificate
2001-03-20
2002-07-02
Wong, Don (Department: 2821)
Electric lamp and discharge devices: systems
Discharge device load
Plural gases or vapors in the discharge device
C313S332000, C313S623000
Reexamination Certificate
active
06414451
ABSTRACT:
BACKGROUND OF THE INVENTION
The invention relates to a high-pressure discharge lamp having a ceramic discharge vessel through whose wall at least one electrical feedthrough is guided, the electrical feedthrough and the discharge vessel being connected in a gas-tight fashion by means of a sealing compound, the electrical feedthrough being formed from a first individual part made from niobium, tantalum or from an alloy based on niobium and/or tantalum and from at least one second individual part, which is made from a material which is more resistant to oxidation than niobium, tantalum or an alloy based on niobium and/or tantalum. The region of the connection between the first and the second individual parts is either covered by the sealing compound or formed by the sealing compound, and a discharge electrode is arranged at one end, arranged in the discharge vessel, of the electrical feedthrough.
Such a lamp is disclosed in the German Utility Model Application G 86 28 310, niobium being used in conjunction with tungsten, a material which is more resistant to oxidation, as electrical feedthrough for high-pressure discharge lamps. Use is made in this case of a gas-tight seal and an arrangement of very complex design, in order to protect the niobium against corrosion by aggressive metal halides in the discharge vessel. The tungsten projects into the discharge vessel in this case, while the niobium projects from the discharge vessel. The niobium outside the discharge vessel is unprotected against oxidative attack. It is therefore assumed that the discharge vessel must be operated in a fashion insulated from the atmosphere in an outer protective capsule not illustrated here.
EP 930 639 A1 discloses a lamp in which an electrical feedthrough made from a glass-tantalum mixture is used together with a quartz glass vessel, the concentration of the tantalum changing along the electrical feedthrough.
Fusing occurs between the electrical feedthrough and quartz glass vessel only in a region in which the content of tantalum in the SiO
2
is less than 2 vol %. The end of the electrical feedthrough, which contains a high proportion of tantalum, projects in this case out of the quartz glass vessel and is only partially coated with an anti-oxidation layer made from glass, metal oxide or noble metal.
Again, components made from niobium are used in GB 2 178 230 A as electrical feedthroughs for a discharge lamp. The use of such a discharge lamp in a temperature range of 200-300° C., and/or in an atmosphere with a high moisture content is chiefly recommended in conjunction with an outer capsule which protects the electrical feedthroughs against oxidation and corrosion. Thus, one example shows the discharge lamp and the electrical feedthroughs inside a protective capsule made from glass which is filled with inert gas and sealed in a gas-tight fashion.
U.S. Pat. No. 5,404,078 discloses a high-pressure discharge lamp having a ceramic discharge vessel and having a metal halide filling, which is arranged in a protective vessel made from quartz glass. The ends of the ceramic discharge vessel are sealed with ceramic stoppers into each of which an electrical feedthrough with a round diameter is sintered in a gas-tight fashion. The electrical feedthroughs are designed such that the end of the electrical feedthrough which projects into the discharge vessel and is in contact with the metal halide filling is formed from corrosion-resistant tungsten, molybdenum, rhenium or from alloys of these metals. The other end of the electrical feedthroughs, which projects out of the discharge vessel and is surrounded by the protective vessel made from quartz glass, is formed, for example, from niobium, which is arranged in a fashion protected against corrosion by the metal halide filling.
The problem of the extremely low oxidation resistance of niobium and its alloys even at low temperatures starting from approximately 400° C. is known from the publication entitled “Niobium in High Temperature Applications” written by H. Inouye, which is based on the symposium held in San Francisco held on 8.11.1981 (Proceedings of the International Symposium). The metal tantalum, which is closely related to niobium, behaves in a way similar thereto. This property greatly limits the field of use of these metals and their alloys at elevated temperatures. Thus, coatings are already known which increase the resistance to oxidation. These are normally silicide or aluminide coatings, which can be applied only with a high outlay. In addition, the brittleness of these layers results in impairment of the thermal shock resistance accompanied by the formation of cracks or instances of chipping of the layer. The intended protective function of the coating is thereby lost, and the oxidation of the metal can proceed starting from the flaws in the layer.
SUMMARY OF THE INVENTION
It is the object of the present invention to provide a further possibility of increasing the resistance to oxidation and corrosion of electrical feedthroughs which are arranged in or on high-pressure discharge lamps, in particular on sodium high-pressure discharge lamps.
The problem is solved, firstly, in that the first individual part projects at least partially into the discharge vessel, and the second individual part projects at least partially out of the discharge vessel, in that the second individual part penetrates at most 50% of the thickness of the sealing compound, and in that the material which is more resistant to oxidation is a metal or a metal alloy with elements from the groups IVB and/or VIII of the periodic system (in accordance with CVS).
A great advantage of high-pressure discharge lamps with electrical feedthroughs of such configuration is that they can be operated without an additional outer protective encapsulation, for example made from glass. Thus, the external dimensions of the lamp can be of decisively smaller configuration. This is particularly important when there is little space available for the lamp at the place of use.
It is particularly preferred when the elements Ti and/or Pt and/or Pd and/or Ni and/or Fe and/or Ir are contained in the metal which is more resistant to oxidation and/or in the metal alloy which is more resistant to oxidation. It has proved to be particularly useful when the first individual part is formed from niobium and the second individual part is formed from titanium.
The following table is intended to illustrate purely by way of example the increased resistance to oxidation of the materials listed above by contrast with niobium, tantalum, or alloys based on niobium and/or tantalum. Titanium and niobium alloy NbZr1 were selected as reference materials:
TABLE 1
Increase in weight of titanium and NbZrl in (%) as a function of the storage
time in air at elevated temperatures
(— signifies: no measurement carried out)
Temperature
400° C.
500° C.
600° C.
650° C.
700° C.
Time
Ti
NbZrl
Ti
NbZrl
Ti
NbZrl
Ti
NbZrl
Ti
NbZrl
1 h
0
0.039
0.035
3.206
0.051
—
0.058
—
0.122
—
6 h
0
3.295
0
—
0.136
—
0.188
—
0.417
—
13 h
0
—
0
—
0.17
—
0.365
—
0.762
—
29 h
0
—
0
—
0.356
—
1.005
—
1.188
—
69 h
—
—
—
—
0.285
—
—
—
—
—
100 h
—
—
—
—
0.392
—
—
—
—
—
The problem is solved, furthermore, by virtue of the fact that the first individual part projects at least partially into the discharge vessel, and the second individual part projects at least partially out of the discharge vessel, in that the second individual part penetrates at most 50% of the thickness of the sealing compound, and in that the material which is more resistant to oxidation is made from a ceramic. Particular preference is given here to ceramic made from Al
2
O
3
and/or MoSi
2
and/or (Mo, W)Si
2
and/or SiC and/or Si
3
N
4
. It is also greatly advantageous here that a lamp having electrical feedthroughs of such configuration can be operated without additional outer protective encapsulation, for example made from glass, and so the external dimensions are small.
The electrical feedthrough can be designed at least partially in the form of a cylinder and/or a tubelet. One
Baake Reinhard
Lupton David Francis
Cohen & Pontani, Lieberman & Pavane
Tran Thuy Vinh
W. C. Heraeus Holding GmbH & Co. KG
Wong Don
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