Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Ion-exchange polymer or process of preparing
Patent
1975-07-07
1978-07-18
Schofer, Joseph L.
Synthetic resins or natural rubbers -- part of the class 520 ser
Synthetic resins
Ion-exchange polymer or process of preparing
210198C, 521 29, 521 32, C08J 520
Patent
active
041014600
ABSTRACT:
An ion exchange composition comprising an insoluble substrate of a synthetic resin having ion exchanging sites at least on its available surface; and a finely divided, insoluble material comprising synthetic resin particles of from about 0.1 to about 5 microns median diameter (with respect to volume) having, at least on their outer surfaces, ion exchanging sites which attract the ion exchanging sites of the substrate, irreversibly attached as a monolayer to the available surface of the substrate. The composition is used for removal and separation of ions, and is especially useful in liquid ion exchange chromatography. For example, a chromatographic separation of halide ions is effected with high speed and resolution by contacting an aqueous solution thereof with a bed of the ion exchange composition which consists of surface sulfonated resin beads of a styrene-divinylbenzene copolymer to the surface of which is irreversibly attached a monolayer of quaternary ammonium-bearing styrene-divinylbenzene copolymer resin particles in the hydroxy form, and then eluting the bed with an aqueous sodium hydroxide solution.
REFERENCES:
patent: 3041292 (1962-06-01), Hatch
patent: 3250704 (1966-05-01), Levendusky
patent: 3332890 (1967-07-01), Hatch
patent: 3485658 (1969-04-01), Iler
patent: 3782075 (1974-01-01), Kirkland
patent: 3957698 (1976-05-01), Hatch
Angewandte Chemie 71:215-217 (1959), Grubhofer--Dow Chem. Trans.
Small Hamish
Stevens Timothy S.
Fifield David H.
Kulkosky Peter F.
Schofer Joseph L.
The Dow Chemical Company
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