High performance fuel processing system for fuel cell power...

Gas: heating and illuminating – Methane -containing product – or treatment or recovery process – Process including chemical reaction

Reexamination Certificate

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C422S177000, C422S198000, C422S198000, C423S246000, C429S010000

Reexamination Certificate

active

06932848

ABSTRACT:
A fuel processing system (FPS) (110) is provided for a fuel cell power plant (115) having a fuel cell stack assembly (CSA) (56). A water gas shift (WGS) reaction section (12, 120) of the FPS (110) reduces the concentration of carbon monoxide (CO) in the supplied hydrocarbon reformate, and a preferred oxidation (PROX) section (40) further reduces the CO concentration to an acceptable level. The WGS section (12, 120) includes a reactor (124) with a high activity catalyst for reducing the reformate Co concentration to a relatively low level, e.g., 2,000 ppmv or less, thereby relatively reducing the structural volume of the FPS (110). The high activity catalyst is active at temperatures as low as 250° C., and may be a noble-metal-on-ceria catalyst of Pt and Re on a nanocrystaline, cerium oxide-based support. Then only a low temperature PROX reactor (46) is required for preferential oxidation in the FPS (110).

REFERENCES:
patent: 3565830 (1971-02-01), Keith et al.
patent: 3825501 (1974-07-01), Muenger
patent: 3870455 (1975-03-01), Hindin
patent: 4021366 (1977-05-01), Robin et al.
patent: 4157316 (1979-06-01), Thompson et al.
patent: 4170573 (1979-10-01), Ernest et al.
patent: 4171288 (1979-10-01), Keith et al.
patent: 4297246 (1981-10-01), Cairns et al.
patent: 4308176 (1981-12-01), Kristiansen
patent: 4331565 (1982-05-01), Schaefer et al.
patent: 4476246 (1984-10-01), Kim et al.
patent: 4585752 (1986-04-01), Ernest
patent: 4587231 (1986-05-01), Sawamura et al.
patent: 4629612 (1986-12-01), van der Wal et al.
patent: 4835132 (1989-05-01), Sambrook
patent: 4868148 (1989-09-01), Henk et al.
patent: 5039503 (1991-08-01), Sauvion et al.
patent: 5057483 (1991-10-01), Wan
patent: 5073532 (1991-12-01), Domesle et al.
patent: 5139992 (1992-08-01), Tauster et al.
patent: 5254519 (1993-10-01), Wan et al.
patent: 5275997 (1994-01-01), Ganguli et al.
patent: 5464606 (1995-11-01), Buswell et al.
patent: 5480854 (1996-01-01), Rajaram et al.
patent: 5490977 (1996-02-01), Wan et al.
patent: 5491120 (1996-02-01), Voss et al.
patent: 5492878 (1996-02-01), Fujii et al.
patent: 5500198 (1996-03-01), Liu et al.
patent: 5516597 (1996-05-01), Singh et al.
patent: 5532198 (1996-07-01), Chopin et al.
patent: 5744118 (1998-04-01), Imamura et al.
patent: 5788950 (1998-08-01), Imamura et al.
patent: 5830425 (1998-11-01), Schneider et al.
patent: 5843195 (1998-12-01), Aoyama
patent: 5895772 (1999-04-01), Grigorova et al.
patent: 5945369 (1999-08-01), Kimura et al.
patent: 5948683 (1999-09-01), Koermer et al.
patent: 5990040 (1999-11-01), Hu et al.
patent: 6033634 (2000-03-01), Koga
patent: 6040265 (2000-03-01), Nunan
patent: 6107240 (2000-08-01), Wu et al.
patent: 6120923 (2000-09-01), Van Dine et al.
patent: 6120925 (2000-09-01), Kawatsu et al.
patent: 6133194 (2000-10-01), Cuif et al.
patent: 6159256 (2000-12-01), Bonville, Jr. et al.
patent: 6204219 (2001-03-01), Brezny et al.
patent: 6299994 (2001-10-01), Towler et al.
patent: 6322917 (2001-11-01), Acker
patent: 6326329 (2001-12-01), Nunan
patent: 6409939 (2002-06-01), Abdo et al.
patent: 6455182 (2002-09-01), Silver
patent: 6562088 (2003-05-01), Ukai et al.
patent: 6692545 (2004-02-01), Gittleman et al.
patent: 6733552 (2004-05-01), Taguchi et al.
patent: 6787118 (2004-09-01), Roark et al.
patent: 2001/0002248 (2001-05-01), Ukai et al.
patent: 2002/0071806 (2002-06-01), Sabacky et al.
patent: 2002/0073895 (2002-06-01), Barnes et al.
patent: 2002/0110519 (2002-08-01), Ying et al.
patent: 2002/0131915 (2002-09-01), Shore et al.
patent: 2003/0129100 (2003-07-01), Ukai et al.
patent: 2003/0235526 (2003-12-01), Vanderspurt et al.
patent: 2004/0048114 (2004-03-01), Shore
patent: 0298351 (1989-01-01), None
patent: 1 046 612 (2000-10-01), None
patent: 1 256 545 (2001-07-01), None
patent: 1 161 991 (2001-12-01), None
patent: 1 256 545 (2002-11-01), None
patent: 10202101 (1998-08-01), None
patent: 1133294 (1999-12-01), None
patent: 2000-178007 (2000-06-01), None
patent: WO 96/23573 (1996-08-01), None
patent: WO 97/44123 (1997-11-01), None
patent: WO 01/03828 (2001-01-01), None
Journal of Catalysis 96, 285-287 (1985) Methanation and Water-Gas Shift Reaction over Pt/CeO2.
S. Hilaire, “A comparative study of water-gas shift reaction over ceria supported metallic catalysts”, Applied Catalysis A: General 215 (2001), pp. 271-278.
Qi Fu, “Nanostructured Au-CeO2 catalysts for low-temperature water-gas shift”, Catalysis Letters, vol. 77, No. 1-3, (2001), pp. 87-95.
S. Hilaire, “A comparative study of water-gas shift reaction over ceria supported metallic catalysts”, Applied Catalysis A: General 215 (2001), pp. 271-278.
Qi Fu, “Nanostructured Au-CeO2 catalysts for low-temperature water-gas shift”, Catalysis Letters, vol. 77, No. 1-3, (2001), pp. 87-95.
E. S. Putna, et al, “Ceria films on zirconia substrates: models for understanding oxygen storage properties”, Catalysis Today, 50 (1999), pp. 343-352.
Paolo Fornasiero, et al, “On the rate determining step in the reduction of CeO2-ZrO2 mixed oxides”, Applied Catalysis B: Environmental, 22 (1999), pp. L11-L14.
S. Rossignol, et al, “Preparation of zirconia-ceria materials by soft chemistry”, Catalysis Today, 50 (1999), pp. 261-270.
T. Bunluesin, et al, “Studies of the water-gas shift reaction on ceria-supported Pt, Pd, and Rh: implications for oxygen storage properties”, Applied Catalysis, B: Environmental, (1998), pp. 107-114.
G. Colon, et al, “Surface and structural characterization of CeZr1-xO2 CEZIRENCAT mixed oxides as potential three-way catalyst promoters”, J. Chem. Soc., Faraday Trans., 94 (1998), pp. 3717-3726.
O. A. Kirichenko, et al, “Effect of coprecipitation conditions on the surface area, phase composition, and reducibility of Ce2-ZrO2-Y2O3 materials for automotive three-way catalysts”, Preparation of Catalysts VII, B. Delmon, et al, editors, (1998), pp. 411-420.
Carla E. Hori, et al, “Thermal stability of oxygen strorage properties in a mixed CeO2-ZrO2 system”,Applied Catalysts B: Environmental, 16 (1998), pp. 105-11.
Lj. Kundakovic, et al, “Cu- and Ag-modified cerium oxide catalysts for methane oxidation”,Journal of Catalysis179 (1998), pp. 203-221.
Daniela Terribile, et al, “The preparation of high surface area CeO2-ZrO2 mixed oxides by a surfactant-assisted approach”,Catalysis Today, 43 (1998), pp. 79-88.
Lj. Kundakovic, et al, “Reduction characteristics of copper oxide in cerium and zirconium oxide systems”,Applied Catalysis A: General, 171 (1998), pp. 13-29.
G. Vlaic, et al, “Relationship between the zirconia-promoted reduction in the Rh-loaded Ce0.5Zr0.5O2 mixed oxide and the Zr-O local structure”,Journal of Catalysis168 (1997), pp. 386-392.
Polona Vidmar, et al, “Effects of trivalent dopants on the redox properties of Ce0.6Zr0.4O2 mixed oxide”,Journal of Catalysis171 (1997), pp. 160-168.
H. Cordatos, et al, “Effects of ceria structure on oxygen migration for Rh/ceria catalysts”,J. of Physical Chemistry, (1996) 100, pp. 785-789.
P. Fornasiero, et al, “Modification of the redox behaviour of CeO2 induced by structural doping with ZrO2”,J. of Catalysis164 (1996), pp. 173-183.
Yuhan Sun, et al, “Importance of homogeneity in the stabilisation of high surface area CeO2-ZrO2 aerogels”,J. of Material Chemistry6(6) (1996), pp. 1025-1029.
P. Fornasiero, et al, “Rh-loaded CeO2-ZrO2 solid solutions as highly efficient oxygen exchangers: dependence of the reduction behavior and the oxygen storage capacity on the structural properties”,J. of Catalysis151 (1995), pp. 168-177.

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