High performance filters comprising inorganic fibers having...

Details High performance filters comprising inorganic fibers having... High performance filters comprising inorganic fibers having...

2000-02-04

2002-05-21

Drodge, Joseph W. (Department: 1723)

Liquid purification or separation

Filter

Supported, shaped or superimposed formed mediums

C210S500230, C210S500260, C210S200000, C210S502100, C210S503000, C210S505000, C428S306600, C428S408000, C501S094000, C501S095100, C502S224000, C502S326000, C502S527120

Reexamination Certificate

active

06390304

ABSTRACT:

FIELD OF THE INVENTION
The present invention is directed to novel high performance filters having characteristics suitable for use in various filtration applications, such as microfiltration. More particularly, this invention is directed to a novel high performance filter media system comprising a fiber reinforced matrix composite that is low in cost, durable, resistant to chemicals and high temperatures, not subject to particulation, high in mechanical strength and separation efficiency, and biocompatible.
BACKGROUND OF THE INVENTION
The prior art provides many types of materials which remove, filter, or capture gases and particulate materials. These filters of the art, while fairly effective in the applications for which they were designed, do not offer the efficiency, performance, and durability demanded by new, high performance applications.
The demand for higher quality materials, reduced manufacturing costs, and environmentally clean processes is forcing industry to move away from traditional methods of separation and purification, such as distillation and pasteurization, towards the use of filtration. Filter systems are now capable of offering low energy, more efficient, and environmentally friendly operations. Unfortunately, the widespread use of high performance filtration is restricted by the lack of suitable filter media materials. Such media must offer low cost; durability; chemical resistance, particularly to acids and alkalis; resistance to high temperatures, for both operation and sterilization purposes; no particulation (i. e., release of filter media particles into the filtrate stream); mechanical strength to cope with pressure swings; separation efficiency, particularly for particles in the 0.1 to 100 microns range; and biocompatibility for certain applications such as the filtration of blood.
Table 1 below lists the currently available filter media materials together with their advantages and disadvantages.
TABLE 1
Currently Available Filter Media Materials
Applications
Maximum
material is suitable
Operating
Principle
Principle
Material
for
Temp. (° C.)
Advantages
Disadvantages
Cotton
Aqueous solutions,
 90
Inexpensive
Subject to fungal attack
oils, fats, and waxes
Nylon
Acids,
150
High strength and
Absorbs water and
petrochemicals, and
flexibility; long
subject to attack by
solvents
life, and good
alkalis
solids discharge
Polyester
Acids, common
100
Good strength and
Subject to attack by
organic solvents, and
flexibility
alkalis
oxidizing agents
PVC
Acids and alkalis
 90
May become brittle;
and poor heat resistance
PTFE
Virtually all
200
Extreme chemical
High cost
chemicals
resistance
Polyethylene
Acids and alkalis
 70
Softens at moderate
temperatures
Polypropylene
Acids, alkalis, and
130
Not suitable for use
solvents (except
with aromatics and
aromatics and
chlorinated solvents
chlorinated solvents)
Glass fiber
Concentrated hot
250
Wide range of hot
Subject to attack by
acids, and chemical
or cold solvents
alkalis and some acids
solutions
Stainless Steel
Most environments
>300 
Good resistance to
Expensive and size
most environments
range limitations
Ceramics
Most environments
1000 
Good resistance to
Expensive and complex
most environments
manufacturing methods
required; and poor
durability
As presented in Table 1, no one filtration material offers the required balance of properties needed for new, high performance applications.
Ceramic filter media have made some inroads, however their acceptance is hampered by the following: high cost because expensive and complex manufacturing processes are required; susceptibility to attack by alkalis; limited durability because of their inherent brittleness; and difficulties in controlling pore size distribution and permeability, which are critical aspects of high performance filter media.
High temperature composite materials, in which a ceramic or carbon matrix is reinforced with a continuous fiber, are used in a variety of applications. They are most commonly used in aircraft brakes. In this application, the braking material is made from a carbon matrix reinforced with carbon fibers (carbon/carbon or C/C). Such materials have a high mechanical strength and are capable of operating at extreme temperatures, up to 3000° C. in a non oxidizing atmosphere. Composites in which both the reinforcing fiber and the matrix are both ceramic are used in specialty applications. In particular, they are used in aircraft engine parts where strength at high temperatures and low weight are needed.
Such high temperature composite materials do offer some potential for use as filter media. For example, carbon/carbon composites, due to the excellent balance of properties, have found use as a filter support. U.S. Pat. No. 4,944,996 discloses the use of a carbon/carbon support intended to receive a mineral membrane for separation procedures. U.S. Pat. No. 4,500,328 discloses the use of carbon/carbon composites to filter radioactive waste, and the use of activated carbon fiber to increase surface area. U.S. Pat. No. 5,183,546 discloses an electrochemical filter consisting of an electrically conductive fibrous material that contains microscopic particles of carbon or active charcoal.
Ceramic matrix composites have been used as hot gas filters. U.S. Pat. No. 4,968,467 discloses the use of refractory ceramic fibers matted together with a high temperature binder, such as colloidal alumina or silica, to form a tube like “candle filter.” U.S. Pat. No. 5,196,120 discloses the use of a ceramic fiber-ceramic composite filter composed of ceramic fibers, preferably texturized, a carbonaceous layer thereover, and a silicon carbide coating over the carbonaceous layer, which coats substantially all of the fibers. A strong, light weight filter is achieved.
Despite the advances made in the art, of which the above are examples, ceramic and carbon based composite materials have not previously been suited to high performance filtration. This is especially true for microfiltration because of the difficulties in achieving the required porosity, surface area and permeability required for efficient separation. In general, pore size distribution and the ability of the filter to retain or capture particulate matter is a function of the fiber diameter (
Filters and Filtration Handbook, Third Edition
, 1992). In the art outlined above, fiber diameters range from 7 microns for conventional carbon fibers to 100 microns and above for some ceramic fibers. The diameters of such fibers are too large. These fibers do not provide the small pores required for efficient small particulate retention.
U.S. Pat. No. 5,138,546 discloses the addition of small carbon or charcoal particles which improves surface area and particle capture ability. However, this type of filter is not suitable for most high performance applications, particularly in the foodstuffs and chemical industries. These structures exhibit poor bonding of the particles to the substrate. In addition, there is a tendency for such constructions to particulate, in other words, release undesired particles into the filtrate stream. Also, the addition of such particles can only be performed on a random basis. There is little control with respect to uniformity and positioning.
In light of the disadvantages of the prior art, there is therefore presently a need to develop high performance filter media capable of operating in the microfiltration regime which offer: low cost; durability; chemical resistance, particularly to acids and alkalis; resistance to high temperatures, for both operation and sterilization purposes; no particulation (i.e., release of filter media particles into the filtrate stream); mechanical strength to cope with pressure swings; separation efficiency, particularly for particles in the 0.1 to 100 micron range; and biocompatibility for certain applications, such as the filtration of blood.
SUMMARY OF THE INVENTION
The present invention is directed to a novel high performance filter system having characteristics suitable for use in various filtration applications, such as micro

Affiliated with

Also associated with

Rating

High performance filters comprising inorganic fibers having... does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with High performance filters comprising inorganic fibers having..., we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and High performance filters comprising inorganic fibers having... will most certainly appreciate the feedback.

Rate now

Comments { 0 }

Profile ID: LFUS-PAI-O-2828789