High performance elastic composite materials made from high...

Surgery – Means and methods for collecting body fluids or waste material – Absorbent pad for external or internal application and...

Reexamination Certificate

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C604S385240, C604S373000, C604S385270

Reexamination Certificate

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06323389

ABSTRACT:

FIELD OF THE INVENTION
The present invention relates to composite elastic materials produced from polymers whose number and/or weight average molecular weight is characterized as the entanglement molecular weight, which is also a function of the microstructure of the polymer in a continuous filament stretch bonded laminate process. More particularly, the present invention relates to a nonwoven laminate of continuous filaments bonded to a meltblown layer, both of these layers being stretched and bonded between two layers of spunbonded material, the resulting web being relaxed prior to being wound on a takeup roll. The material is useful as side panels in training pants, and other articles where elastic material capable of prolonged performance at body temperature.
BACKGROUND
A key aspect of a disposable garment is fit over time at use temperature, i.e., the body temperature. Therefore, elastic properties are measured at body temperature to simulate the expected end use conditions. Such garments often include portions which are subject to repeated stretch and relaxation stresses over an extended period of time. Examples include garment materials, pads, wound dressings and wraps, diapers and personal care products where elasticity may be desired. A particular example is the side panel of training pants and incontinence undergarments. This side panel is typically made of an elastic material, often a composite, which can withstand the repeated stretch and resulting stress at body temperature.
At body temperature certain elastic properties of polymers become important. Two specific elastic properties measured are the rate of load decay and the load loss observed over a period of twelve hours at body temperature.
A conventional method of forming such elastic composite material is one in which nonelastic spunbond facing materials are combined with an elastomer layer, comprised of high performance elastic strands. The laminate of the elastic strands is made by; bonding the strand to the facings using a meltblown polymer containing a tackifier and/or a pressure sensitive adhesive. This produces a nonwoven elastic composite with desirable elongations, along with improved mechanical and body conformance properties. This process is sometimes known as a continuous filament stretch bonded laminate (“CFSBL”) process.
SUMMARY OF THE INVENTION
The present invention comprises a continuous feed spun bonded laminate having improved elastic properties measured at body temperature. In a preferred embodiment the laminate comprises a layer of filaments formed by a continuous filament process, to which is bonded a layer of meltblown fibers. This composite material is then sandwiched between two layers of spunbond fibers after being stretched. The resulting layers are then passed between a pair of niprolls and the resulting laminate is then relaxed prior to winding on a takeup roll.
A unique feature of the present invention is the incorporation of a triblock copolymer as the filament layer. The triblock polymer is preferably of a triblock polystyrene-poly(ethylene/propylene)-polystyrene (“SEPS”) copolymer or a polystyrene-poly(ethylene/butylene)-polystyrene (“SEBS”) copolymer, each having a number average molecular weight of about 81,000 g/mol. The weight percent of styrene is approximately 18% and the weight percent of ethylene/propylene is approximately 82%. Conventional triblock polymer is typically in the 61,000 g/mol range. The molecular weight increase in the polymer midblock, while holding the molecular weight of the styrene block constant, increases the entanglement density, polymer chain persistence length and the relaxation time. The resulting laminate load decay rate and load loss measurements over a period of 12 hours at body temperature showed marked improvement over known CFSBL product. The laminate is particularly useful as side panel material in training pants because of the resistance to sagging at body temperature.


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