Organic compounds -- part of the class 532-570 series – Organic compounds – Heavy metal containing
Patent
1996-11-15
1998-07-28
Hollinden, Gary E.
Organic compounds -- part of the class 532-570 series
Organic compounds
Heavy metal containing
564158, 568 14, 568 17, 568426, 549523, 549337, 424 165, 424 936, 534 10, 534 15, C07F 1500, C07C23300, C07C 4500, A61K 5100
Patent
active
057864969
ABSTRACT:
The present invention provides a new tetradentate bis-amido bis-alkoxo, 1,2-(bis-2,20diphenyl-2-hydroxyethanamido)benzene (H.sub.4 PHAB) and various derivatives thereof. This ligand is able to stabilize high valen metal oxo complexes by providing strong sigma donor ligands and through the use of steric bulk to prevent decomposition via formation of the .mu.-oxo dimers. Disclosed are novel metal oxo structural chemistry and oxidation reactions carried out with the novel metal oxo complexes.
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Fackler Nathanael L. P.
MacDonnell Frederick M.
O'Halloran Thomas V.
Hartley Michael G.
Hollinden Gary E.
Northwestern University
Timmer Edward J.
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