High overbased metal sulfurized alkyphenates

Solid anti-friction devices – materials therefor – lubricant or se – Lubricants or separants for moving solid surfaces and... – Sulfurized compound of indeterminate structure – which is a...

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508332, C10M13502

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active

057599661

ABSTRACT:
Process for preparing high overbased metal sulfurized alkylphenates, wherein a majority of the alkalinity is provided by at least a stoichiometric excess of metal. The process is characterized by a sulfurization reaction using a promoter, followed by overbasing with carbon dioxide, a polyamine, and additional metal base in the presence of an alkylene glycol under reactive conditions at temperatures in the range of about from 150.degree. C. to 190.degree. C. The process affords a metal sulfurized phenate product which is substantially insensitive to overcarbonation, which exhibits low corrosive wear, and which exhibits high rates of acid neutralization. These compositions are useful in the formulation of marine cylinder lubricants.

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