Chemistry of hydrocarbon compounds – Plural serial diverse syntheses – With hydrocarbon recycle from later to earlier synthesis
Patent
1979-05-15
1980-07-08
Crasanakis, George
Chemistry of hydrocarbon compounds
Plural serial diverse syntheses
With hydrocarbon recycle from later to earlier synthesis
585331, 585644, 585717, C07C 362, C07C 350
Patent
active
042118859
ABSTRACT:
High octane gasoline is produced from cat cracked gasoline by cleaving the C.sub.5 olefins in the gasoline with ethylene in a first disproportionation zone. The effluent is separated to produce a C.sub.5.sup.+ stream, a first butenes stream and an ethylene-propylene stream. The ethylene-propylene stream is passed to a second disproportionation or cleavage zone along with additional propylene supplied from an external source. The effluent is separated to produce ethylene which is passed to the first disproportionation zone and a second stream of butenes. The butenes stream are combined and passed to an alkylation zone where it is alkylated with isobutane. The alkylate and remaining gasoline (C.sub.5.sup.+ stream) can be combined to produce a product higher in octane value than cat cracked gasoline.
REFERENCES:
patent: 3763032 (1973-10-01), Banks
patent: 3767565 (1973-10-01), Banks
patent: 3785956 (1974-01-01), Banks
patent: 3785957 (1974-01-01), Banks
Crasanakis George
Phillips Petroleum Company
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