High modulus, high ductility polyolefins

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Mixing of two or more solid polymers; mixing of solid...

Reexamination Certificate

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Details

C525S053000, C526S065000, C526S124900, C526S125300, C526S348000

Reexamination Certificate

active

07348381

ABSTRACT:
Provided herein are propylene polymers which are capable of being used as thermoplastic polyolefins just as they emerge from the reactor system described, without further compounding of components which substantially modify the physical properties of the polymers, as such compounding is required of polymers of the prior art. Polymers according to the invention unexpectedly possess both low temperature ductility and high flexural modulus, which properties were related in inverse proportion to one another in the polymers of the prior art.

REFERENCES:
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patent: 6284833 (2001-09-01), Ford et al.
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patent: 0 361 494 (1996-02-01), None
“Microstructure Distribution of Polypropylenes Obtained in the Presence of Traditional Phthalate/Silane and Novel Diether Donors: A toll for Understanding the Role of Electron Donors in MgCI2-supported Ziegler-Natta Catalysts” Morini et al. in the journal “Macromolecules” 1996, 29, 5770-57767/15/96.
“Diether Based Catalysts: The New Ziegler/Natta Generation for PP” by George van Os given at SPO in 1998.
“Propene polymerization with MgCI2-supported catalysts: effects of using a diether as external donor” by Chadwick et al, from the journal Macromolecul. Chem. Phys. 198, 1181-1188 (1997).

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