High melt strength polypropylene

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymerizing in tubular or loop reactor

Reexamination Certificate

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Details

C526S065000, C526S066000, C526S067000, C526S068000, C526S351000, C526S905000, C525S053000, C525S240000

Reexamination Certificate

active

06875826

ABSTRACT:
The present invention concerns a high melt strength propylene polymer or copolymer suitable for manufacturing foams and thermoformed product exhibiting a melt strength of at least 3 g and comprising a high molar mass portion and a low or medium molar mass portion. The polymers are produced by subjecting propylene and optionally other olefins to polymerization in a plurality of polymerization reactors connected in series, employing different amounts of hydrogen as a molar mass modifier in at least two of the reactors, and carrying out the polymerization reaction in the presence of a catalyst system capable of catalyzing the formation of a high molar mass polymerization product having a MFR2of less than 0.1 g/l0 min and a low or medium molar mass polymerization product having a MFR2of more than 0.5 g/10 min.

REFERENCES:
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First page of FI 86866 corresponds to US 5,234,879.
First page of FI 900836 corresponds to US 5,047,485.
First page of FI 96615 corresponds to EP 0 627 449 A1.
First page of FI 95387 corresponds to EP 0 607 703 A1.
First page of FI 88047 corresponds to WO 92/19653.
First page of FI 88048 corresponds to WO/ 92/19658.
Macromol. Symp. 98 (1995) 73-89 Albizzati et al. “Recent Advances in Propylene Polymerization with MgCl2 Supported Catalysts”.
Makromol. Chem. 192 (1991) 2857-2863 Harkonen et al. “External silane donors in Ziegler-Natta catalysis. An approach to the optimum structure of the donor”.
Encyclopedia of Pol. Science & Eng. 2nd Edition, vol. 6 544-559 “Ethylene-Propylene Elastomers”.

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