High gas adsorption metal-organic framework

Details High gas adsorption metal-organic framework High gas adsorption metal-organic framework

2006-04-07

2010-02-16

Johnson, Edward M (Department: 1793)

Catalyst, solid sorbent, or support therefor: product or process

Solid sorbent

Organic

C502S439000

Reexamination Certificate

active

07662746

ABSTRACT:
A gas storage material contains a metal-organic framework that includes a plurality of metal clusters and a plurality of charged multidentate linking ligands that connect adjacent metal clusters. Each metal cluster includes one or more metal ions and at least one open metal site. The metal-organic framework includes one or more sites for storing molecular hydrogen. A hydrogen storage system using the hydrogen storage material is provided.

REFERENCES:
patent: 3144418 (1964-08-01), Hill et al.
patent: 4359327 (1982-11-01), Armand et al.
patent: 5629523 (1997-05-01), Ngo et al.
patent: 5648508 (1997-07-01), Yaghi
patent: RE35908 (1998-09-01), Kitaguchi et al.
patent: 5862796 (1999-01-01), Seki et al.
patent: 5880471 (1999-03-01), Schelten et al.
patent: 5940460 (1999-08-01), Seidel et al.
patent: 6072181 (2000-06-01), Hassard et al.
patent: 6312902 (2001-11-01), Shultz et al.
patent: 6348607 (2002-02-01), Müller et al.
patent: 6479680 (2002-11-01), Bassler et al.
patent: 6479826 (2002-11-01), Klann et al.
patent: 6518441 (2003-02-01), Grosch et al.
patent: 6545281 (2003-04-01), McGregor et al.
patent: 6617467 (2003-09-01), Mueller et al.
patent: 6624318 (2003-09-01), Mueller et al.
patent: 6727371 (2004-04-01), Muller et al.
patent: 6893564 (2005-05-01), Mueller et al.
patent: 6929679 (2005-08-01), Muller et al.
patent: 6930193 (2005-08-01), Yaghi et al.
patent: 6965026 (2005-11-01), Zaworotko et al.
patent: 7008607 (2006-03-01), Muller et al.
patent: 7119219 (2006-10-01), Muller et al.
patent: 2003/0078311 (2003-04-01), Muller et al.
patent: 2004/0110950 (2004-06-01), Li et al.
patent: 2004/0225134 (2004-11-01), Yaghi et al.
patent: 2004/0265670 (2004-12-01), Mueller et al.
patent: 2 387 122 (2001-02-01), None
patent: 2 414 756 (2003-01-01), None
patent: 2 414 779 (2003-01-01), None
patent: 44 08 772 (1994-09-01), None
patent: 197 23 950 (1998-12-01), None
patent: 198 35 907 (2000-02-01), None
patent: 198 47 629 (2000-04-01), None
patent: 199 36 547 (2001-02-01), None
patent: 100 15 246 (2001-10-01), None
patent: 100 32 884 (2002-01-01), None
patent: 100 32 885 (2002-01-01), None
patent: 101 11 230 (2002-09-01), None
patent: 101 43 195 (2003-03-01), None
patent: 00 557 116 (1993-08-01), None
patent: 0 727 608 (1996-08-01), None
patent: 0 790 253 (1997-08-01), None
patent: 1 280 090 (2003-01-01), None
patent: 2004024247 (2004-01-01), None
patent: WO 97/46711 (1997-12-01), None
patent: WO 99/05151 (1999-02-01), None
patent: WO 00/78837 (2000-12-01), None
patent: WO 01/16209 (2001-03-01), None
patent: WO 01/27186 (2001-04-01), None
patent: WO 02/070526 (2002-09-01), None
patent: WO 02/088148 (2002-11-01), None
patent: WO 03/035717 (2003-05-01), None
patent: WO 03/044228 (2003-05-01), None
U.S. Appl. No. 10/270,642, filed Oct. 16, 2002, Mueller et al.
U.S. Appl. No. 10/611,863, filed Jul. 3, 2003, Mueller et al.
U.S. Appl. No. 10/983,629, filed Nov. 9, 2004, Hesse et al.
Bondi, A., “van der Waals Volumes and Radii,” Journal of Phys. Chem., Mar. 16, 1964, vol. 68, No. 3, pp. 441-451.
Bennett, J.M. and J.V. Smith, “Positions of Cations and Molecules in Zeolites with the Faujastie-Type Framework I. Dehydrated Ca-Exchanged Faujasite,” Mat. Res. Bull., vol. 3, No. 8, 1968, pp. 633-642.
Hoskins, B.F. and R. Robson, “Infinite Polymeric Frameworks Consisting of Three Dimensionally Linked Rod-Like Segments,” J. Am. Chem. Soc., 1989, vol. 111, pp. 5962-5964.
Fagan, P.J. and M.D. Ward, “Building Molecular Crystals,” Sci. Am., Jul. 1992, pp. 48-54.
Stein, A., S.W. Keller and T.E. Mallouk, “Turning Down the Heat, Design and Mechanism in Solid-State Synthesis,” Mar. 12, 1993, vol. 259, pp. 1558-1564.
Russell, V.A., C.C. Evans, W.Li and M.D. Ward, “Nanoporous Molecular Sandwiches: Pillared Two-Dimensional Hydrogen-Bonded Networks with Adjustable Porosity,” Science, Apr. 25, 1997, vol. 276, pp. 575-579.
Husing, N. and U. Schubert, “Aerogels-Airy Materials: Chemistry, Structure, and Properties,” Agnew. Chem. Int. Ed., 1998, vol. 37, pp. 22-45.
Menon, V.C. and S. Komarneni, “Porous Adsorbents for Vehicular Natural Gas Storage: A Review,” J. of Porous Materials, 1998, vol. 5, pp. 43-58.
Jones, C.W., K. Tsuji and M.E. Davis, “Organic-Functionalized Molecular Sieves as Shape-Selective Catalysts,” Nature, May 7, 1998, vol. 393, pp. 52-54.
Fujita, M., “Self-Assembly of [2]Catenanes Containing Metals in Their Backbones,” Accounts of Chemical Research, 1999, vol. 32, No. 1, pp. 53-61.
Li, H., M. Eddaoudi, M. O'Keeffe and O.M. Yaghi, “Design and Synthesis of an Exceptionally Stable and Highly Porous Metal-Organic Framework,” Nature, Nov. 18, 1999, vol. 402, pp. 276-279.
Li, H., C.E. Davis, T.L. Groy, D.G. Kelley and O.M. Yaghi, Coordinately Unsaturated Metal Centers in the Extended Porous Framework of Zn3(BDC)3·6CH3OH (BDC=1,4-Benzenedicarboxylate), J. Am. Chem. Soc., 1998, vol. 120, pp. 2186-1287.
Kiang, Y.-H, G.B. Gardner, S. Lee, Z. Xu and E.B. Lobkovsky, “Variable Pore Size, Variable Chemical Functionality, and an Example of Reactivity Within Porous Phenylacetylene Silver Salts,” J. Am. Chem. Soc., 1999, vol. 121, pp. 8204-8215.
Eddaoudi, M., H. Li and O.M. Yaghi, “Highly Porous and Stable Metal-Organic Frameworks: Structure Design and Sorption Properties,” J. Am. Chem. Soc., 2000, vol. 122, pp. 1391-1397.
Noro, S., S. Kitagawa, M. Kondo and K. Seki, “A New, Methane Adsorbent, Porous Coordination Polymer [{CuSiF6(4,4-bipyridine)2}n],” Angew. Chem. Int. Ed., 2000, vol. 39, No. 12, pp. 2081-2084.
Yaghi, O.M., M. O'Keeffe and M. Kanatzidis, “Design of Solids from Molecular Building Blocks: Golden Opportunities for Solid State Chemistry,” J. Solid State Chem., 2000, vol. 152, pp. 1-2.
Reineke, T.M., M. Eddaoudi, D. Moler, M. O'Keeffe and O.M. Yaghi, “Large Free Volume in Maximally Interpenetrating Networks: The Role of Secondary Building Units Exemplified by Tb2(ADB)3[CH3]2SO]4·16 [(CH3)2SO]1,” J. Am. Chem. Soc., 2000, vol. 122, pp. 4843-4844.
Eddaoudi, M., D.B. Moler, H. Li, B. Chen, T.M. Reineke, M. O'Keeffe and O.M. Yaghi, “Modular Chemistry: Secondary Building Units as a Basis for the Design of Highly Porous and Robust Metal-Organic Carboxylate Frameworks,” Acc. Chem. Res., 2001, vol. 34, pp. 319-330.
Seki, K., “Design of an Adsorbent with an Ideal Pore Structure for Methane Adsorption Using Metal Complexes,” Chem. Commun., 2001, 1496-1497.
Kim, J., B. Chen, T.M. Reineke, H. Li, M. Eddaoudi, D.B. Moler, M. O'Keeffe and O.M. Yaghi, “Assembly of Metal-Organic Frameworks from Large Organic and Inorganic Secondary Building Units: New Examples and Simplifying Principles for Complex Structures,” J. Am. Chem. Soc., 2001, vol. 123, pp. 8239-8274.
Guillou, N., Q. Gao, P.M. Forster, J. Chang, M. Norgues, S. Park, G. Ferey and A.K. Cheetham, “Nickel(ii) Phosphate VSB-5: A Magnetic Nanoporous Hydrogenation Catalyst with 24-Ring Tunnels,” Angew. Chem. Int. Ed., 2001, vol. 40, No. 15, pp. 2831-2834.
Naumov, P., G. Jovanovski, M. Ristova, I.A. Razak, S. Cakir, S. Chantrapromma, H. Fun and S. Weng Ng, “Coordination of Deprotonated Saccharin in Copper(II) Complexes. Structural Role of the Saccharinate Directed by the Ancillary N-heterocyclic Ligands,” Z. Anorg. Allg. Chem., 2002, vol. 628, pp. 2930-2939.
Wallner, H. and K. Gatterer, “Growth of Pure Ni(OH)2Single Crystals from Solution—Control of the Crystal Size,” Z. Anorg. Allg. Chem., 2002, vol. 628, pp. 2818-2820.
Patoux, S. and C. Masquelier, “Lithium Insertion into Titanium Phosphates, Silicates and Sulfates,” Chemistry of Materials, 2002, vol. 14, No. 12, pp. 5057-5068.
Rosi, N., M. Eddaoudi, J. Kim et al., “Infinite Secondary Building Units & Forbidden Catenation in Metal-Organic Frameworks”, Angew. Chem. Int. Ed., 2002, 41, No. 2, pp. 284-285.
Eddaoudi, M., J. Kim, N. Rosi et al., “Systematic Design

Affiliated with

Also associated with

Rating

High gas adsorption metal-organic framework does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with High gas adsorption metal-organic framework, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and High gas adsorption metal-organic framework will most certainly appreciate the feedback.

Rate now

Comments { 0 }

Profile ID: LFUS-PAI-O-4185300