Metal treatment – Stock – Magnetic
Reexamination Certificate
1999-02-05
2001-09-11
Sheehan, John (Department: 1742)
Metal treatment
Stock
Magnetic
C420S090000, C420S093000, C420S104000, C420S118000, C420S126000, C420S128000
Reexamination Certificate
active
06287395
ABSTRACT:
BACKGROUND OF THE INVENTION
The invention relates to a high-energy weldable soft magnetic steel with high toughness in the heat-affected zone of weld joints, high specific electric resistance to reduce eddy currents, aging resistance and weathering resistance as well as its use for part of magnetic suspension railways which absorb carrying, guiding or driving forces, in particular side guide rails.
During the welding of structural steels, a coarse-grained structure is produced in a narrow zone next to the melt line as a result of the thermal stress of the material, which impairs the toughness properties. The size of the grain and the width of the coarse-grain zone are influenced by the energy per unit length during welding. With the increase of the energy per unit length, the grain is increased in size and, as a result, the energy absorbed in notched bar impact work deteriorates. As on the one hand the economical aspects of the welding is increased with rising energy per unit length and on the other hand a high toughness of the heat-affected zone is desired for the security of the component, there is a high demand for steels which are weldable with high energy per unit length without any permitted loss of toughness in the heat-affected zone, “Thyssen Techn. Berichte” (Thyssen Technical Reports), Volume 1/85, pages 42 to 49.
During the production of fine-grain structural steels the influence of fine precipitations, which can impair the austenite grain growth have long been used. Nitrides, carbides and carbonitrides of niobium and titanium as well as aluminum nitrides prevent the growth of austenite grains by obstructing the grain boundary movement. In the case of thermal stress caused during the welding, most precipitations dissolve and thus become ineffective. Only titanium nitride remains stable even at temperatures up to over 1400° C. The effect of titanium nitrides on the obstruction of the austenite grain growth depends on their quantity, size and distribution. The dispersion of titanium nitrides is influenced by the content of titanium and nitrogen, as well as by the cooling conditions of the steel after the casting. Fine titanium nitride precipitations with a particle size of less than 0.020 &mgr;m originate at titanium contents of less than 0.03% and a titanium
itrogen ratio of 2 to 3.4. Under this prerequisite, the most effective obstruction in the austenite grain growth during the welding is achieved.
Steels whose alloy content is adjusted to corrosion resistance and the magnetic properties cannot be welded with high energy per unit length without losses in toughness in the heat-affected zone. The present invention is therefore based on the object of providing a soft magnetic steel which, on the one hand, can be processed with high energy per unit length by high-energy welding without any loss in toughness and, on the other hand, fulfils the requirements concerning high specific electric resistance, resistance to aging and weathering.
SUMMARY OF THE INVENTION
This object is achieved in accordance with the invention by a steel with the following chemical composition (in mass per cent):
0.65
to
<1.0%
chromium
>1.0
to
2.0%
silicon
0.25
to
0.55%
copper
0.003
to
0.008%
nitrogen
0.15
to
<0.6%
manganese
0.02
to
0.07%
aluminum
soln.
0.01
to
0.02%
titanium
0
to
0.15%
carbon
0
to
0.045%
phosphorus
balance iron and unavoidable impurities.
This steel preferably has the following composition:
0.75
to
0.85%
chromium
1.6
to
1.8%
silicon
0.25
to
0.35%
copper
0.003
to
0.008%
nitrogen
0.30
to
0.40%
manganese
0.040
to
0.07%
aluminum
solu.
0.01
to
0.02%
titanium
0.05
to
0.08%
carbon
0.005
to
0.02%
phosphorus
balance iron and unavoidable impurities.
The steel in accordance with the invention solves the problem. It fulfills, on the one hand, the analytical requirements for high-energy welding and, on the other hand, the high requirements placed on a material, for example, for bearing and guiding elements of magnetic suspension railways concerning high specific electric resistance, resistance to aging and weathering.
A soft magnetic steel of similar composition is known from DE 30 09 234 C2, but which is not suitable for high-energy welding, i.e. welding with high energy per unit length. High energy per unit length during the welding processing of these steels is of special commercial interest owing to the rapid welding speed in view of the long travel routes of the magnetic suspension railway.
The steel in accordance with the invention is produced by casting, rolling, normalizing, or by normalizing rolling and accelerated cooling. In order to fulfill the requirements concerning the suitability for the high-energy welding, the titanium content of the steel in accordance with the invention is fixed preferably at 0.01 to 0.02% and the nitrogen content to 0.005 to 0.008% with a titanium
itrogen ratio of preferably 2 to
4. The most effective obstruction to the austenite grain growth during the welding with high heat introduction is achieved under this requirement.
As a result of the inventive alloying of a soft magnetic steel with titanium, the aforementioned improvement of the weldability is combined uniquely with a simultaneous high electric resistance. The high electric resistance ensures a low power consumption during the operation of the magnetic suspension railway by minimizing the eddy current losses.
The steel in accordance with the invention can be processed considerably more efficiently, and as a result of its outstanding electrical properties, causes lower eddy current losses under operating conditions.
As a result of its aforementioned profile of properties, the steel in accordance with the invention id highly suitable for parts of magnetic suspension railways which must absorb bearing, guiding or driving forces, such as lateral guide rails.
REFERENCES:
patent: 4091147 (1978-05-01), Kanazawa et al.
patent: 4388122 (1983-06-01), Sudo et al.
patent: 4537644 (1985-08-01), Tominaga et al.
patent: 2 071 149 A (1981-09-01), None
patent: 08-041582-A (1996-02-01), None
Baumgardt et al., “verbesserung der Zahighkeitseigenschaften in der Warmeeinflussone von SchweiBverbindungen aus Feikornbaustahlen”, Thyssen Technische Berichte, pp. 42 to 48, Jun. 1996.*
Patent Abstracts of Japan, vol. 096, No. 006, Jun. 28, 1996 (Abstract of JP 08 041582 A cited above).*
“Effects of titanium on magnetic properties of semi-processed non-oriented electrical steel sheets,” T. Nakayama et al.,Journal of Materials Science 32 (1997), pp. 1055-1059.
Schriever Udo
Tschersich Hans-Joachim
Proskauer Rose LLP
Sheehan John
Thyssen Stahl AG
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