High energy insensitive cyclic nitramines

Organic compounds -- part of the class 532-570 series – Organic compounds – Four or more ring nitrogens in the bicyclo ring system

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149 92, C07D25100, C07D25118, C07D25148

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active

049373404

ABSTRACT:
Cyclic nitramines of the formula ##STR1## in which R.sup.1, R.sup.2 and R.sup.3 are independently selected from the group consisting of H, NO and NO.sub.2, and acid salts of the compound in which R.sup.1, R.sup.2 and R.sup.3 are each H, are disclosed. These compounds are useful as components in energetic compositions, including rocket and gun propellants and explosives, and are of particular interest due to their combination of high energy output and insensitivity. Compounds in which R.sup.3 is H or NO are further useful as intermediates in the preparation of those in which R.sup.3 is NO.sub.2. Also disclosed is a method for producing such compounds involving the reaction between hexamethylenetetramine and nitroguanidine.

REFERENCES:
patent: 4562188 (1985-12-01), Kuhla et al.

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