High efficiency, high temperature catalyst for polymerizing olef

Details High efficiency, high temperature catalyst for polymerizing olef High efficiency, high temperature catalyst for polymerizing olef

1980-09-16

1982-02-09

Garvin, Patrick

Compositions

Preservative agents

Anti-oxidants or chemical change inhibitants

252431R, C08F 464

Patent

active

043149120

ABSTRACT:
Compositions exhibiting high catalytic activity in the polymerization of .alpha.-olefins at temperatures above 140.degree. C. are provided by reacting a transition metal compound such as tetra(isopropoxy)titanium, an organomagnesium component such as a hydrocarbon soluble complex of dialkyl magnesium and an alkyl aluminum, e.g., di-n-butylmagnesium.x triethylaluminum and a hydrogen halide or an active hydrocarbyl halide such as t-butyl chloride. Polymerization processes employing this catalyst composition do not require conventional catalyst removal steps in order to provide polymers having suitable color and other physical characteristics.

REFERENCES:
patent: 2959576 (1960-11-01), Payne
patent: 2971950 (1961-02-01), Nolta et al.
patent: 3101327 (1963-08-01), Lynn
patent: 3161628 (1964-12-01), Dort et al.
patent: 3385841 (1968-05-01), Bruton et al.
patent: 3472910 (1969-10-01), Favis
patent: 3737393 (1973-06-01), De Vries
patent: 3878124 (1975-04-01), Durand et al.
patent: 4120820 (1978-10-01), Birkelbach
patent: 4135046 (1979-01-01), Harris et al.
Mole et al., Organoaluminum Compounds, Elsevier Pub. Co., N.Y., N.Y. (1972), pp. 88, 89, 189, 274 & 281.
Wakefield, Organometal Chem. Rev. 1, (1966), pp. 148-149.
Coates et al., Organometallic Compounds, vol. 1, Methuen & Co., Ltd., London, 3rd Ed. (1967) p. 78.
Texas Alkyls, Inc., Technical Brochure, "Aluminum Alkyl . . . Specification, Properties and Procedures", (1973).

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