High discharge capacity lithium battery

Chemistry: electrical current producing apparatus – product – and – Current producing cell – elements – subcombinations and... – Electrode

Reexamination Certificate

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C429S207000, C429S209000, C427S126100

Reexamination Certificate

active

08007940

ABSTRACT:
A lithium/iron disulfide electrochemical battery cell with a high discharge capacity. The cell has a lithium negative electrode, an iron disulfide positive electrode and a nonaqueous electrolyte. The iron disulfide of the positive electrode has a controlled average particle size range which allows the electrochemical cells to exhibit desired properties in both low and high rate applications. In various embodiments, the iron disulfide particles are wet milled, preferably utilizing a media mill or milled utilizing a non-mechanical mill such as a jet mill, which reduces the iron disulfide particles to a desired average particle size range for incorporation into the positive electrode.

REFERENCES:
patent: 4071665 (1978-01-01), Garth
patent: 4379815 (1983-04-01), Bubnick
patent: 4629666 (1986-12-01), Schlaikjer
patent: 4902589 (1990-02-01), Dahn
patent: 4935317 (1990-06-01), Fauteux
patent: 5051183 (1991-09-01), Takita et al.
patent: 5143805 (1992-09-01), Anderman et al.
patent: 5219683 (1993-06-01), Webber
patent: 5229227 (1993-07-01), Webber et al.
patent: 5240655 (1993-08-01), Troffkin et al.
patent: 5281491 (1994-01-01), Rein et al.
patent: 5290414 (1994-03-01), Marple
patent: 5453333 (1995-09-01), Takauchi et al.
patent: 5667911 (1997-09-01), Yu et al.
patent: 5691077 (1997-11-01), Yu
patent: 5786396 (1998-07-01), Takita et al.
patent: 5830554 (1998-11-01), Kaimai et al.
patent: 5853633 (1998-12-01), Kono et al.
patent: 5922492 (1999-07-01), Takita et al.
patent: 5952120 (1999-09-01), Yu et al.
patent: 6057060 (2000-05-01), Yu
patent: 6057061 (2000-05-01), Callahan et al.
patent: 6080507 (2000-06-01), Yu
patent: 6083644 (2000-07-01), Watanabe
patent: 6132654 (2000-10-01), Yu
patent: 6153133 (2000-11-01), Kaimai et al.
patent: 6180280 (2001-01-01), Spotnitz
patent: 6203947 (2001-03-01), Peled et al.
patent: 6218054 (2001-04-01), Webber
patent: 6245272 (2001-06-01), Takita et al.
patent: 6287719 (2001-09-01), Bailey
patent: 6287730 (2001-09-01), Callahan et al.
patent: 6319865 (2001-11-01), Mikami
patent: 6322923 (2001-11-01), Spotnitz et al.
patent: 6346350 (2002-02-01), Call et al.
patent: 6368742 (2002-04-01), Fisher et al.
patent: 6432586 (2002-08-01), Zhang
patent: 6475679 (2002-11-01), Tsutiya et al.
patent: 6479190 (2002-11-01), Wensley
patent: 6566012 (2003-05-01), Takita et al.
patent: 6602593 (2003-08-01), Callahan et al.
patent: 6616715 (2003-09-01), Kitoh et al.
patent: 6630257 (2003-10-01), Ye et al.
patent: 7312002 (2007-12-01), Aoshima
patent: 7491378 (2009-02-01), Yamamoto
patent: 7687189 (2010-03-01), Wu
patent: 2002/0018929 (2002-02-01), Dai et al.
patent: 2002/0039677 (2002-04-01), Iwamoto et al.
patent: 2002/0064706 (2002-05-01), Zhang et al.
patent: 2002/0122985 (2002-09-01), Sato et al.
patent: 2002/0134964 (2002-09-01), Christian et al.
patent: 2003/0072995 (2003-04-01), Nark et al.
patent: 2004/0121234 (2004-06-01), Le
patent: 2005/0106458 (2005-05-01), Eguchi et al.
patent: 2005/0277023 (2005-12-01), Marple et al.
patent: 2006/0035147 (2006-02-01), Lam et al.
patent: 2008/0118836 (2008-05-01), Hwang
patent: 0068230 (1983-01-01), None
patent: 1097962 (2001-05-01), None
patent: 1296389 (2003-03-01), None
patent: 1829140 (2007-05-01), None
patent: 59012566 (1984-01-01), None
patent: 59226468 (1984-12-01), None
patent: 61151968 (1986-07-01), None
patent: 2005053067 (2005-06-01), None
Yang Shao-Horn and Quinn C. Horn, “Chemical, structural, and electrochemical comparison of natural and synthetic FeS2 pyrite in lithium cells”. Electrochimica Acta (2001) 2613-2621, Jan. 26, 2001.
L.A. Montoro and J.M. Rosolen, “Gelatin/DMSO: a new approach to enhancing the performance of a pyrite electrode in a lithium battery”. Solid State Ionics 159 (2003) 233-240, Nov. 25, 2002.
E. Strauss, D. Golodnitsky, K. Freedman, A. Milner, E. Peled, “To the electrochemistry of pyrite in Li/solid composite-polymer-electrolyte battery”. Journal of Power Sources 115 (2003) 323-331, Dec. 16, 2002.
Gowri S. Nagarajan, J.W. Van Zee and R.M. Spotnitz, “A Mathematical Model for Intercalation Electrode Behavior, I. Effect of Particle-Size Distribution on Discharge Capacity”. J. Electrochem. Soc., vol. 145, No. 3, Mar. 1998.
Eveready Battery Company, Inc. response to Preliminary Opinion of the Opposition Division, Aug. 24, 2010, 4 pages.
Gillette response to Preliminary Opinion of the Opposition Division, Aug. 25, 2010, 5 pages.
Eveready Battery Company, Inc. response to opponent late submission, Sep. 20, 2010, 5 pages.
Patent Cooperation Treaty (PCT), International Search Report and Written Opinion for Application No. PCT/US2005/011367, filed Apr. 1, 2005, mailed Jan. 5, 2006, 11 pgs., European Patent Office, Netherlands.
Shao-Horn, et al. “Reinvestigation of Lithium Reaction Mechanisms in FeS2 Pyrite at Ambient Temperature”. Journal of the Electrochemical Society, 149 (12) A1547-A1555 (2002).
Li et al. “Rate Capabilities of Nanostructured LiMn2O4 Electrodes in Aqueous Electrolyte,” Journal of the Electrochemical Society, 147 (6) 2044-2049 (2000).
Kim et al., “Synthesis and Lithium Intercalation Properties of Nanocrystalline Lithium Iron Oxides,” Journal of the Electrochemical Society, 146 (12) 4371-4374 (1999).
“Advantages of the Zinger Horizontal Media Mill,” Morehouse-COWLES, www.morehousecowles.com.
“Hi Energy Lithium,” Application Manual. Energizer Power Systems, pp. 1-20.
Statement of Grounds of Appeal of The Gillette Company, Mar. 15, 2011, 13 pages.
Declaration of Nikolai Issaev, Nov. 5, 2009. Declaration of Adrian John Fisher, May 15, 2009. Carpmaels & Ransford, London.
Opposition by The Gillette Company. Dec. 22, 2009.
Opposition by The Gillette Company. Mar. 9, 2009.
“Improvements in Energizer's L91 Li-FeS2 AA Cells”, Andrew Webber. Proceedings of the 41st Power Sources Conference, Jun. 14-17, 2004.
Advanced Program, 41st Power Sources Conference, Jun. 14-17, 2001.
“Preparation of Iron Disulfide and its Use for Lithium Batteries”, Chiaki Iwakura, Noriyuki Isobe and Hideo Tamura.
“Nano-FeS2 for Commercial LiFeS2 Primary Batteries”, Journal of the Electrochemical Society, Yang Shao-Horn, Steve Osmialowski, and Quinn C. Horn, Oct. 9, 2002.

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