High concentration encapsulation by interfacial polycondensation

Chemistry: fertilizers – Processes and products – Forms or conditioning

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71 93, 71118, 71120, 71121, 71DIG1, 264 47, 424 19, 424 32, 42840221, A01N 3718, A01N 3722, B01J 1302

Patent

active

046407090

ABSTRACT:
This invention relates to a process for encapsulation, and particularly to the production of small or minute capsules constituted by a skin or thin wall of polymeric material e.g., polyurea, polyamide, polysulfonamide, polyester, polycarbonate, or polyurethane, which involves first providing an aqueous solution (continuous phase liquid) containing an emulsifier which is a water soluble, alkylated polyvinyl pyrrolidone polymer which will form a stable oil-in-water emulsion under the process conditions described herein. A discontinuous (immiscible or organic) phase liquid containing a water-immiscible material which is the material to be encapsulated, plus a first shell wall component; is dispersed in the aqueous liquid to form an oil-in-water emulsion. The second shell wall component is added to the oil-in-water emulsion whereupon the first shell wall component reacts with the second shell wall component to form a solid polycondensate shell wall about the material to be encapsulated. The capsules formed may be directly used as in the form of an aqueous suspension.

REFERENCES:
patent: 3417054 (1968-12-01), Merijan et al.
patent: 3423381 (1969-01-01), Merijan et al.
patent: 3429827 (1969-02-01), Ruus
patent: 3577515 (1971-05-01), Vandegaer
patent: 3660304 (1972-05-01), Matsukawa
patent: 3754062 (1973-08-01), Kobayashi
patent: 4280833 (1981-07-01), Beestman et al.
patent: 4285720 (1981-08-01), Scher
patent: 4497793 (1985-02-01), Simkin
P. W. Morgan, "Interfacial Polycondensation, a Versatile Method of Polymer Preparation", Society Plastics Engineers Journal 15, pp. 485-495, (1959).
Asaji Kondo, "Microcapsule Processing and Technology", pp. 35-45, (1979).

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