Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – At least one aryl ring which is part of a fused or bridged...
Patent
1989-12-08
1992-02-18
Marquis, Melvyn I.
Synthetic resins or natural rubbers -- part of the class 520 ser
Synthetic resins
At least one aryl ring which is part of a fused or bridged...
525393, 524424, 524428, 524439, C08K 338
Patent
active
050895524
ABSTRACT:
The hydrolytic polycondensation of a monomer of ##STR1## wherein R.sup.1, R.sup.2, R.sup.3, and R.sup.4 are independently alkyl groups containing from 1 to 4 carbon atoms, R.sup.a, R.sup.b, R.sup.c, and R.sup.d are independently alkenyl or alkyl groups containing from 2 to 6 carbon atoms with the proviso that at least one of R.sup.a, R.sup.b, R.sup.c, or R.sup.d group is an alkenyl group; can be carried out directly in the presence of a phenolic resin. This in situ polymerization reaction results in the formation of a new family of polysilazoxane-modified phenolic resins. Modified phenolic resins may also be prepared by the controlled hydrolysis of the above monomers in the presence of initiators. The polysilazoxane so formed is blended into a phenolic resin. The organic soluble thermosetting resins exhibit synergistic char yields of 63 to 80 wt. % (1500.degree. C./N.sub.2).
REFERENCES:
patent: 4722988 (1988-02-01), Porte et al.
Effects of Molecular Weight and Cross-Linking on Two Pre-Ceramic Polymers--by Wm. Toreki and Christopher D. Batich.
Hudak Daniel J.
Marquis Melvyn I.
Shust Nestor W.
The B. F. Goodrich Company
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