High capacity adsorption media and method of producing

Catalyst – solid sorbent – or support therefor: product or process – Solid sorbent – Having specifically intended extraneously added iron group...

Reexamination Certificate

Rate now

  [ 0.00 ] – not rated yet Voters 0   Comments 0

Details

Reexamination Certificate

active

07368412

ABSTRACT:
A method of producing an adsorption medium to remove at least one constituent from a feed stream. The method comprises dissolving at least one metal compound in a solvent to form a metal solution, dissolving polyacrylonitrile into the metal solution to form a PAN-metal solution, and depositing the PAN-metal solution into a quenching bath to produce the adsorption medium. The at least one constituent, such as arsenic, selenium, or antimony, is removed from the feed stream by passing the feed stream through the adsorption medium. An adsorption medium having an increased metal loading and increased capacity for arresting the at least one constituent to be removed is also disclosed. The adsorption medium includes a polyacrylonitrile matrix and at least one metal hydroxide incorporated into the polyacrylonitrile matrix.

REFERENCES:
patent: 4039444 (1977-08-01), Bory et al.
patent: 4576969 (1986-03-01), Echigo et al.
patent: 5591346 (1997-01-01), Etzel et al.
patent: 5788826 (1998-08-01), Nyberg
patent: 5895796 (1999-04-01), Mouri et al.
patent: 6001258 (1999-12-01), Sluys et al.
patent: 6045697 (2000-04-01), Girot et al.
patent: 6136199 (2000-10-01), SenGupta et al.
patent: 6232265 (2001-05-01), Bruening et al.
patent: 6290848 (2001-09-01), Tanner et al.
patent: 6641719 (2003-11-01), Naito
patent: 6656350 (2003-12-01), Kitakaze
patent: 6881327 (2005-04-01), Tanner et al.
patent: 6881333 (2005-04-01), Ozeki et al.
patent: 2002/0121470 (2002-09-01), Mann et al.
patent: 2045994 (1995-10-01), None
Chanda, et al., “Ligand Exchange Sorption of Arsenate and Arsenite Anions by Chelating Resins in Ferric Ion Form: I. Weak-Base Chelating Resin Dow XFS-4195,” Reactive Polymers, 7 (1988) pp. 251-261, no month.
Chanda, et al., “Ligand Exchange Sorption of Arsenate and Arsenite Anions by Chelating Resins in Ferric Ion Form: II. Iminodiacetic Chelating Resin Chelex 100,” Reactive Polymers, 8 (1988) pp. 85-95, no month.
DeMarco, et al., “Arsenic Removal Using a Polymeric/Inorganic Hybrid Sorbent,” Water Research 37 (2003) pp. 164-176, no month.
Ramana, et al., Removing Selenium(IV) and Arsenic (V) Oxyanions with Tailored Chelating Polymers, Journal of Environmental Engineering, vol. 118, No. 5. Sep./Oct. 1992, pp. 755-775.
Thieme, Trevor, “Newsfiles, Like a Cup of Arsenic? Oh, You've Already Got Some” Popular Science, http://www.popsci.com/popsci/science/article/0,12543,195220,00.html, 2003, 2 pages, no month.
Janney et al., “Structure of synthetic 2-line ferrihydrite by electron nanodiffraction,” American Mineralogist, vol. 85, pp. 1180-1187, 2000, no month.
Janney et al., “Structure of synthetic 6-line ferrihydrite by electron nanodiffraction,” American Mineralogist, vol. 86, pp. 327-335, 2001, no month.
McKenzie et al., “Direct electrochemistry of nanoparticulate Fe2O3 in aqueous solution and adsorbed onto tin-doped indium oxide,” Pure Apl. Chem., vol. 73, No. 12, pp. 1885-1894, 2001, no month.
Navratil, James D., “Adsorption and Nanoscale Magnetic Separation of Heavy Metals from Water,” Clemson University, 8 pages, no date.
Parkinson, Gordon, “Crystallisation Program,” pp. 74-83,, 2004, no month.
Bowen, H. J. M. (1979). Elemental Chemistry of the Elements, Academic Press, London and New York, 13-62, no month.
Pandey, P. K., Yadav, D., Bhui, A. Arsenic Contamination of the Environment. A New Perspective from Central-East India. Environ. Int., 28, 235-245, 2002.
Nickson, R., McArthur, J, Burgess, W. Arsenic Poisoning in Bangladesh Groundwater. Nature, 395, 338-348, 1998.
Das, D., Samanta, G., Mandal, B. K., Chowdhury, T. R., Chandra, C. R., Chowdhurry, P. P. , Basu, G. K., Chakraborti, D. Arsenic in Groundwater in Six Districts of West Bengal, India. Environ. Geochem. Hlth., 18, 5-15, 1996.
Masud, K. Arsenic in Groundwater and Health Problems in Bangladesh. Water Research, 34, 304-310, 2000.
Del Razo, L. M., Arellano, M.A., Cebrian, M. E. The Oxidation States of Arsenic in Well Water from a Chronic Arsenicism Area of Northern Mexico. Environmental Pollution, 64, 143-153, 1990.
Borgono, J. M., Vincent, P., Venturino, H., Infante, A. Arsenic in the Drinking Water of the City of Antofagasta: Epidemiological and Clinical Study before and after Installation of a Treatment Plant. Environmental Health Perspectives, 19, 103-105, 1997.
Chen, S. L., Dzeng, S. R., Yang, M. H., Chiu,, K. H., Shieh, G. M., Wai, C. M. Arsenic Species in Groundwaters of he Blackfoot Disease Area, Taiwan. Environmental Science and Technology, 28, 877-881, 1994.
Arsenic in Drinking Water: 2001 Update, National Research Council, National Academy Press, 24-69, 2001.
SenGupta, A.K., Greenleaf, J. E. Arsenic in Subsurface Water: Its Chemistry and Removal by Engineered Processes. Environmental Separation of Heavy Metals, Edited by A. K. SenGupta, 265-306, Lewis Publishers, CRC Press, Boca Raton, FL, 2002.
PCT International Search Report dated Nov. 10, 2005.
PCT Written Opinion of the International Searching Authority dated Nov. 10, 2005.
Chwirka, J. D., Thomson, B. M., Stomp, J. M. Removing Arsenic from Groundwater. Jour. American WaterWorks Assoc., 92(3), 79-88, 2000.
Schwertmann, U., Cornell, R. M. Iron Oxides in the Laboratory, 2nd Ed., Wiley-Vch, Weinheim, Germany, 5-18, 2000.
Nickolaidis, N. P., Dobbs, G. M., Lackovic, J. A. Arsenic Removal by Zero-Valent Iron: Field, Laboratory and Modeling Studies. Water Research, 37, 1417-1425, 2003.
Chakravarty, S., Durega, V ., Bhattacharyya, G., Maity, S., Bhattacharjee, S. Removal of Arsenic from Groundwater Using Low Cost Ferruginous Manganese Ore. Water Research, 36, 625-632, 2002.
Dambies, L. Existing and Prospective Sorption Technologies for the Removal of Arsenic in Water. Separation Science and Technology, 39(3), 603, 627, 2004.
Tokunaga, S., Wasay, S. A., Park, S. Removal of Arsenic(V) Ion from Aqueous Solutions by Lanthanum Compounds. Water Science and Technology, 35(7), 71-78, 1997.
Wasay, S. A., Haron, J., Uchiumi, A., Tokunaga, S. Removal of Arsenite Ions from Aqueous Solution by Basic Yttrium Carbonate. Water Research, 30(5), 1143-1148, 1996.
Daus, B., Wennrich, R., Weiss, H. Sorption Materials for Arsenic Removal from Water: A Comparative Study. Water Research, 38, 2948-2954, 2004.
Sun, X., Doner, H. E. Adsorption and Oxidation of Arsenite on Geothite. Soil Science, 163(4), 278-287, 1998.
Gulledge, J. H., O'Conner, J. T. Removal of Arsenic(V) from Water by Adsorption on Aluminum and Ferric Hydroxides. Jour. American WaterWorks Assoc., 548-552, 1973.
Roberts, L. C., Hug, S. J., Ruettimann, T., Billah, M., Khan, A. W., Rahman, M. T. Arsenic Removal with Iron (II) and Iron (III) in Waters with High Silicate and Phosphate Concentrations, Environmental Science and Technology, 38, 307-315, 2004.
Jambor, J. L., Dutrizac, J. E. Occurence and Constitution of Natural and Synthetic Ferrihydrite, a Widespread Iron Oxyhydroxide. Chem. Rev., 98, 2549-2585, 1998.

LandOfFree

Say what you really think

Search LandOfFree.com for the USA inventors and patents. Rate them and share your experience with other people.

Rating

High capacity adsorption media and method of producing does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with High capacity adsorption media and method of producing, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and High capacity adsorption media and method of producing will most certainly appreciate the feedback.

Rate now

     

Profile ID: LFUS-PAI-O-3983892

  Search
All data on this website is collected from public sources. Our data reflects the most accurate information available at the time of publication.