High activity olefin polymerization catalyst and process

Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Plural component system comprising a - group i to iv metal...

Reexamination Certificate

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Details

C502S150000, C502S152000, C502S162000, C502S167000, C502S155000, C546S002000, C526S113000

Reexamination Certificate

active

06953764

ABSTRACT:
Group 4 metal complexes useful as addition polymerization catalysts of the formula:whereinG1is a group containing from 1 to 40 atoms not counting hydrogen;T is a divalent bridging group of from 10 to 30 atoms not counting hydrogen, selected from mono- or di-aryl-substituted methylene or silylene groups or mono- or di-heteroaryl-substituted methylene or silylene groups, wherein at least one such aryl- or heteroaryl-substituent is substituted in one or both ortho-positions with a secondary or tertiary alkyl-group, a secondary or tertiary heteroalkyl group, a cycloalkyl group, or a heterocycloalkyl group,G2is a C6-20heteroaryl group containing Lewis base functionality,M is the Group 4 metal,X″″ is an anionic, neutral or dianionic ligand group,x″″ is a number from 0 to 5, andbonds, optional bonds and electron donative interactions are represented by lines, dotted lines and arrows respectively.

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patent: 2002/0142912 (2002-10-01), Boussie et al.
patent: WO 2000 020377 (2000-04-01), None
patent: WO 2002 038628 (2002-12-01), None
patent: WO 2004/024740 (2004-03-01), None

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