Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal
Patent
1976-11-02
1978-10-10
Jiles, Henry R.
Chemistry of carbon compounds
Miscellaneous organic carbon compounds
C-metal
C07D30779, C07D30786
Patent
active
041196465
ABSTRACT:
An olefin is reacted with a source of X free radical in the presence of an ion of manganese, vanadium, or cerium having a valence higher than the lowest valence above the zero valent form of the metal to form derivatives of the olefin that contain one or more functional groups. The free radical X is one that is resistant to substantial oxidation by the ion or the metal and is obtained from ketones, aldehydes, esters, nitriles, nitroparaffins, sulfoxides, thiosulfonic acid esters, alkanesulfonic acids, alkensulfinic acids, and thiols. Hexahydrobenzofuranone compounds are prepared by this reaction.
REFERENCES:
heiba et al., (I) J.A.C.S., 93(2), 1971, pp. 524-527.
Heiba et al., (II) J.A.C.S., 94(8), 1972, pp. 2888-2889.
Heiba et al., (III) J. Organic Chem., 39(23), 1974, pp. 3456-3457.
Brannigan et al., J. Organic Chem., 35(7), 1970, pp. 2339-2344.
Tamara et al., Chem. Pharm. Bull., vol. 19 (1971) pp. 571-574.
Dessau Ralph M.
Heiba El Ahmadi I.
Dentz Bernard
Frilette Vincent J.
Huggett Charles A.
Jiles Henry R.
Mobil Oil Corporation
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