Hexacoordinated ruthenium moderated production of hydrogen perox

Details Hexacoordinated ruthenium moderated production of hydrogen perox Hexacoordinated ruthenium moderated production of hydrogen perox

1979-04-27

1980-06-10

Peters, G. O.

Chemistry of inorganic compounds

Sulfur or compound thereof

Elemental sulfur

423226, 423571, 423584, C01B 15022, C01B 1704

Patent

active

042073057

ABSTRACT:
A process of reacting in the liquid phase a hexacoordinated ruthenium(II) complex with oxygen in the presence of a source of hydrogen ions under conditions forming hydrogen peroxide and the corresponding hexacoordinated ruthenium(III) complex and reacting the hexacoordinated ruthenium(III) complex with hydrogen sulfide to form elemental sulfur and regenerate the hexacoordinated ruthenium(II) complex, the hexacoordinated ruthenium(III) complex having a reduction potential of not more than +0.68. Five or six of the ligands of the ruthenium complexes are non-labile in both valence states.

REFERENCES:
patent: 3923966 (1975-12-01), Vaughan
patent: 3978137 (1976-08-01), Frame
patent: 4007256 (1977-02-01), Kim
Pladziewicz et al., "Inorg. Chem.," vol. 12, No. 3, 1973, pp. 639-643.
Matsubara et al., "Inorg. Chem.," vol. 15, No. 5, 1976, p. 1107-1110.
Brulet et al., "J.A.C.S.," vol. 95, 1973, p. 4758-4759.
Lim, H. S. et al., "Inorg. Chem.," vol. 11, No. 7, 1973, pp. 1397-1403.

Affiliated with

Also associated with

Rating

Hexacoordinated ruthenium moderated production of hydrogen perox does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Hexacoordinated ruthenium moderated production of hydrogen perox, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Hexacoordinated ruthenium moderated production of hydrogen perox will most certainly appreciate the feedback.

Rate now

Comments { 0 }

Profile ID: LFUS-PAI-O-862767