Heteropolymetallic clusters, methods of making such clusters, an

Details Heteropolymetallic clusters, methods of making such clusters, an Heteropolymetallic clusters, methods of making such clusters, an

1985-01-14

1986-09-02

Shine, W. J.

Catalyst, solid sorbent, or support therefor: product or process

Catalyst or precursor therefor

Metal, metal oxide or metal hydroxide

556 14, B01J 2389

Patent

active

046096396

ABSTRACT:
Heteropolymetallic clusters of the formula Pd.sub.2 (Fe).sub.x (CO).sub.4 [CO(NO).sub.2 ].sub.y [bis(diphenylphosphine)methane].sub.2 wherein x is 1 or 2 and y is 0 or 1; x=2 when y=1 and x=1 when y=0; to the method of making such clusters by reacting Pd.sub.2 Cl.sub.2 [bis(diphenylphosphine)methane] with MnFe(CO).sub.3 Z wherein M is an alkaline metal and Z is CO (n=2) or NO (n=1); and to the novel catalysts formed utilizing said clusters.

REFERENCES:
patent: 2857337 (1958-10-01), Hamilton et al.

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