Heteropolyanions with late transition metal addenda atoms...

Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Metal – metal oxide or metal hydroxide

Reexamination Certificate

Rate now

  [ 0.00 ] – not rated yet Voters 0   Comments 0

Details

C502S327000, C502S339000, C502S344000, C562S546000

Reexamination Certificate

active

08080493

ABSTRACT:
The invention relates to polyoxometalates represented by the formula (An)m+[M13X8RqOy]m−or solvates thereof, wherein A represents a cation, n is the number of the cations, m is the charge of the polyanion, M represents a transition metal selected from Pd, Pt, Au, Rh, Ir and mixtures thereof, X represents a heteroatom selected from As, Sb, Bi, P, Si, Ge, B, Al, Ga, S, Se, Te and mixtures thereof, and y is the number of oxygen atoms ranging from 32 to 40, a process for their preparation and their use for the catalytic oxidation of organic molecules.

REFERENCES:
patent: 3206391 (1965-09-01), Gutberlet et al.
patent: 2007/0287853 (2007-12-01), Smith
patent: 0 782 979 (1997-07-01), None
patent: WO 2007/122431 (2007-11-01), None
S.J. Angus-Dunne et al., A. Novel Heteropolymetalate Containing Palladium(s): Synthesis and Crystal Structure of K2Na6[Pd2W10O36]22H2O, 1994, J. Chem. Soc., Chem. Commun., pp. 523-524.
U. Lee et al., Synchrotron structure determination of an α-Keggin doubly PtIV-Substituted silicotungstate, (CH6N3)8[αSiPt2-W10O40]6H2O, Acta Crystallographica, Section C, 2003, C59, m152-m155.
U. Lee, Dipotassium Hexahydrogen-α-hexamolybdoplatinate(IV) Pentahydrate, K2[H6α-PtMo6O2]5H2O, Acta Crystallographica, Section C, 1994, C50, pp. 1657-1659.
U. Lee et al., “Anhydrous octaguanidinium hexatungstoplatinate(IV)”, Acta Crystallographica, Section E, 2003, E59, m116-m118.
U. Lee et al., The Geometrical Isomerization on Acidification in hexamolybdoheteropoly Oxometalate. The Crystal Structure of (NH4)4.5[H3.5αPtMo6O24] 1.5 H2O, (NH4)4[H4β-PtMo6O24] 1.5H2O, and K3.5[H4.5αPtMo6O24]3H2O, Bulletin Korean Chemical Society, 1994, vol. 15, No. 1, pp. 37-45.
L.Bi et al., First Structurally Characterized Palladium(II)-Substituted Polyoxoanion: [Cs2Na(H2O)10Pd3(α-SbIIIW9O33)2]9-, Inorg. Chem., 2004, 43, pp. 3915-3920.
T.M. Anderson et al., A Late-Transition Metal Oxo Complex: K7Na9[O=PtIV(H2O)L2], L=[PW9O34]9-, Science, 2004, vol. 306, pp. 2074-2077.
L. Bi et al., The Palladium(II)-Substituted Tungstosilicate [Cs2K(H2O)uPd2WO(H2O)(A-α-SiW9O34)2]-, Inorg. Chem., 2004, 43, pp. 8367-8372.
L. Bi et al., “The Palladium(II)-Substituted, Lone Pair Containing Tungstoarsenates (III) [Na2(H2O)2PdWO(H2O)(αAsW9O33)2]10- and [Cs2Na(H2O)8Pd3(α-AsW9O33)2]9-”, Eur. J. Inorg. Chem., 2005, pp. 3034-3041.
T.M. Anderson et al., A Palladium-Oxo Complex, Stabilization of This Proposed Catalytic Intermediate by an Encapsulating Polytungstate Ligand, J. Am. Chem. Soc., 2005, 127, pp. 11948-11949.
U. Lee et al., Facile Incorporation of Platinum(IV) into Polyoxometalate Frameworks: Preparation of [H2PtIVV9O28]5- and Characterization by 195Pt NMR Spectroscopy, Angew. Chem. Int. Ed. 2008, 47, pp. 793-796.
W.H. Knoth et al., “Heteropolyanions of the Types M3 (W9PO34)212- and MM′M″(W9PO34)212: Novel Coordination of Nitrate and Nitrite”, Am. Chem. Soc., Inorg. Chem., 1986, 25, pp. 1577-1584.
C.M. Tourne, “Chiral Polytungstometalates [WM3(H2O)2(XW9O34)w]12-(X=M=Zn or CO) and their M-Substituted Derivatives. Syntheses, Chemical, Structural and Spectroscopic Study of some D.L. Sodium and Potassium Salts”, J.Chem. Soc., Dalton Trans., 1991, Issue 1, pp. 143-155.
Polyoxometalate Chemistry: From Topology via Self-Assembly to Applications (Ed.: M.T. Pope, A. Muller), Kluwer, Dordrecht, The Netherlands, 2001.
R. Neumann et al., “Noble Metal (RuIII, PdII, PtII) Substituted “Sandwich” Type Polyoxometalates: Preparation, Characterization, and Catalytic Activity in Oxidations of Alkanes and Alkenes by Peroxides”, Am. Chem. Soc., Inorg. Chem. 1995, 34, pp. 5753-5760.
R. Neumann et al. “Catalytic oxidation with hydrogen peroxide catalyzed by ‘sandwich’ type transition metal substituted polyoxometalates”, Jrnl. of Molecular Catalysis A: Chemical, 117, 1997, pp. 169-183.
U. Schuchardt et al., “Cyclohexane oxidation continues to be a challenge”, Applied Catalysis A: General, 211, 2001, pp. 1-17.
V. Kogan et al., “Preferential catalytic hydrogenation of aromatic compounds versus ketones with a palladium substituted polyoxometalate as pre-catalyst”, J. Chem. 2002, 26, pp. 272-274.
W. Adam et al., “Chiral Hydroperoxides as Oxygen Source in the Catalytic Stereoselective Epoxidation of Allylic Alcohols by Sandwich-Type Polyoxometalates: Control of Enantioselectivity through a Metal-Coordinated Template”, J. Org. Chem., 2003, 68, pp. 8222-8231.
W. Adam et al., “A Highly Chemoselective, Diastereoselective, and Regioselective Epoxidation of Chiral Allylic Alcohols with Hydrogen Peroxide, Catalyzed by Sandwich-Type Polyoxometalates: Enhancement of Reactivity and Control of Selectivity by the Hydroxy Group through Metal-Alcoholate Bonding”, J. Org. Chem., 2003, 68, pp. 1721-1728.
K. Lii et al., “Cs2Pd3(P2O7)2 and Cs2Pd3(As2O7)2: A 3D Palladium Phosphate with a Tunnel Structure and a 2D Palladium Arsenate Containing Strings of Palladium Atoms”, Inorg. Chem., 2004, 43, pp. 2499-2502.
D. Orosel et al., PdAs2O6, the First Paramagnetic Palladium Oxide, Z. Anorg. Allg. Chem., 2006, 632, pp. 1131-1133.
D. Frerichs et al., “Uber das erste Oxopalladat-Arsenat: KMgePd(AsO4)3”, Sect. B, Am. Jrnl. of Chem. Sciences, 1995, 50(6), pp. 867-870.

LandOfFree

Say what you really think

Search LandOfFree.com for the USA inventors and patents. Rate them and share your experience with other people.

Rating

Heteropolyanions with late transition metal addenda atoms... does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Heteropolyanions with late transition metal addenda atoms..., we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Heteropolyanions with late transition metal addenda atoms... will most certainly appreciate the feedback.

Rate now

     

Profile ID: LFUS-PAI-O-4312413

  Search
All data on this website is collected from public sources. Our data reflects the most accurate information available at the time of publication.