Heterogeneous polymerizations in carbon dioxide

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Mixing of two or more solid polymers; mixing of solid...

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525288, 5263297, 526279, C08F25900, C08F27500

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057805539

ABSTRACT:
A method for the polymerization of a monomer is disclosed. The method includes (a) providing a reaction mixture comprising a monomer, a stabilizer precursor, and a polymerization initiator in a polymerization medium comprising carbon dioxide; and then (b) polymerizing the monomer and the stabilizer precursor in the polymerization medium to form a heterogeneous reaction mixture comprising a polymer in the polymerization medium. The stabilizer precursor is covalently bound the polymer to provide an intrinsic surfactant in the polymer, which stabilizes the polymer in the heterogeneous reaction mixture.

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