Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing
Patent
1989-06-13
1991-06-18
McFarlane, Anthony
Organic compounds -- part of the class 532-570 series
Organic compounds
Oxygen containing
568613, 568616, 568624, C07C 4103
Patent
active
050250949
ABSTRACT:
Active-hydrogen compounds, for example, primary and secondary alcohols or diols, are alkoxylated, for example, ethoxylated, using solid anion-bound metal oxide catalysts, such as, zirconium oxysulfate catalyst. Hydrous zirconium oxide is treated with solutions of sulfate phosphate, nitrate or tetrafluoroborate and calcined in air at 300.degree. to 950.degree. C. to produce highly active heterogeneous alkoxylation catalysts. The amorphous catalysts afford narrow molecular weight products. The catalyst can be removed from the product by filtration and reused with no significant loss in activity. Reaction temperatures of 50.degree. to 140.degree. C. are employed for alkoxylation.
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Coon Gerald L.
McFarlane Anthony
Union Carbide Chemicals and Plastics Technology Corporation
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