Chemistry of carbon compounds – Miscellaneous organic carbon compounds
Patent
1974-12-30
1978-01-03
Czaja, Donald E.
Chemistry of carbon compounds
Miscellaneous organic carbon compounds
260 458N, 260 458SN, 260268C, 26029377, 2603067R, 2603265E, 544173, C07D29518, C08K 534, C08K 535, C08K 547
Patent
active
040666140
ABSTRACT:
Compounds of the formula: ##STR1## WHEREIN R.sub.1 and R.sub.2 are each branch-chain alkyl of 3 to 8 carbon atoms and -Het is a nitrogen-containing heterocyclic moiety attached to the carbonyl carbon atom through a heterocyclic nitrogen are useful as light stabilizers in polyolefins. They may be prepared (a) by reacting the 3,5-dialkyl-4-hydroxybenzoyl chloride with the appropriate heterocyclic amine in the presence of an acid acceptor or (b) by reacting the corresponding benzoic acid with the appropriate heterocyclic amine in the presence of a carbodiimide as dehydrating agent.
REFERENCES:
patent: 2906728 (1959-09-01), Schweitzer
patent: 3022302 (1962-02-01), Martensson
patent: 3282939 (1966-11-01), Spivack et al.
patent: 3330859 (1967-07-01), Dexter et al.
patent: 3449419 (1969-06-01), Wechter
patent: 3573304 (1971-03-01), Eberle
Noller, "Chemistry of Organic Compounds", 1957, pp. 160, 249 and 252.
Oppelt John Christian
Susi Peter Vincent
American Cyanamid Company
Czaja Donald E.
Mintz Philip
Van Riet Frank M.
White R. A.
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