Heteroatom containing perfluoroalkyl terminated neopentyl glycol

Details Heteroatom containing perfluoroalkyl terminated neopentyl glycol Heteroatom containing perfluoroalkyl terminated neopentyl glycol

1988-06-20

1990-02-06

Welsh, Maurice J.

Organic compounds -- part of the class 532-570 series

Organic compounds

Sulfur containing

568 29, 568 30, 568 31, 568 32, 568 46, C07C14700

Patent

active

048989819

ABSTRACT:
Heteroatom containing perfluoroalkyl terminated neopentyl glycols of the formula HO[--CH.sub.2 C(CH.sub.2 X--E--R.sub.f).sub.2 CH.sub.2 O].sub.1-3 --H prepared from halogenated neopentyl glycols and thiols of the formula R.sub.f --E--SH, or amines of the formula R.sub.f --E--NH--R wherein R.sub.f is a hydrophonic, olephobic fluoroaliphatic group of up to 20 carbon atoms, E is alkylene of up to 10 carbon atoms, optionally interrupted by up to three groups including --NR, --O, --S--, --SO.sub.2 --, --O.sub.2 C, CONR, and --SO.sub.2 NR, and X is S,SO.sub.2 or NR.sub.2, where R is independently hydrogen, alkyl, or hydroxyalkyl of 1 to 6 carbon atoms are described.
The polymeric reaction products of said fluorinated diols, and optionally other diols with isocyanates to prepare polyurethanes; with amines and isocyanates, to prepare polyureas/polyurethanes; with acids or derivatives, to prepare polyesters or polycarbonates are disclosed. These include polymeric, random or block urethane, and/or urea, and/or ester compositions containing the residue of at least one R.sub.f -neopentyl glycol containing two perfluoroalkylhetero groups.
These polymeric compositions provide improved thermal stability and useful low surface energy coatings with oil, water repellency and soil-release properties for textiles, glass, paper, leather and other materials.

REFERENCES:
patent: 2965659 (1960-12-01), Tiers
patent: 2972638 (1961-02-01), Tiers
patent: 3088849 (1963-05-01), Friedlander
patent: 3145222 (1964-08-01), Brace
patent: 3478116 (1969-11-01), Smeltz
patent: 3544663 (1970-12-01), Hauptschein et al.
patent: 3578701 (1971-05-01), Smeltz
patent: 3655732 (1972-04-01), Scriver
patent: 3728151 (1973-04-01), Sherman et al.
patent: 3758447 (1973-09-01), Falk et al.
patent: 3838165 (1974-09-01), Blochl
patent: 3935277 (1976-01-01), Dear et al.
patent: 4001305 (1977-01-01), Dear et al.
patent: 4046944 (1977-09-01), Mueller et al.
patent: 4054592 (1977-10-01), Dear et al.
patent: 4097642 (1978-06-01), Dear et al.
patent: 4099642 (1978-07-01), Nergard
patent: 4584143 (1986-04-01), Falk
Chem. Abst., 88, 61965g, (1978).
Chem. Abst., 68, 115832u, (1968).
Chem. Abst., 87, 68358z, (1977).

Affiliated with

Also associated with

Rating

Heteroatom containing perfluoroalkyl terminated neopentyl glycol does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Heteroatom containing perfluoroalkyl terminated neopentyl glycol, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Heteroatom containing perfluoroalkyl terminated neopentyl glycol will most certainly appreciate the feedback.

Rate now

Comments { 0 }

Profile ID: LFUS-PAI-O-442788