Herbicide intermediate o-nitrophenyl cyclopropyl ketone and a me

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

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C07C20506

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active

054535450

ABSTRACT:
There is provided o-nitrophenyl cyclopropyl ketone, a key intermediate in the manufacture of the crop-selective, herbicidal agent 1-{[o-(cyclopropylcarbonyl)phenyl]sulfamoyl}-3-(4,6-dimethoxy-2-pyrimidiny l)urea and a method for the preparation of said ketone from dihydro-3-acetyl-2(3H)-furanone and o-nitrobenzoyl halide.

REFERENCES:
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patent: 4075346 (1978-02-01), Sasajima et al.
patent: 5009699 (1991-04-01), Brady et al.
patent: 5107023 (1992-04-01), Brady et al.
Chemical Art & Pharmaceutical Bulletin vol. 9, (1961), pp. 719-721.
Yakugaku Zasshi, vol. 88 (8), pp. 1050-1053 (1968).
Organic Syntheses, Coll. vol. IV, pp. 597-600 (1958).
Cannon et al., "Methyl Cyclopropyl Ketone"; Organic Syntheses, Collective vol. 4, Wiley & Sons (1958).
CA 54:15306i; Bennett et al., 10 Aug. 1960.
CA 105:93715m, Shive et al., Sep. 1986.

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