Chemistry of carbon compounds – Dipeptides – e.g. – aspartame – anserine – carnosine – etc.
Patent
1981-07-06
1984-02-28
Sutto, Anton H.
Chemistry of carbon compounds
Dipeptides, e.g., aspartame, anserine, carnosine, etc.
71 86, 71 87, 2605025D, 260543P, 260940, C07F 946
Patent
active
044341083
ABSTRACT:
The invention relates to novel herbicidally active and plant-growth regulating 2-substituted 5-phenoxyphenylphosphinic acid derivatives of the formula ##STR1## wherein R.sub.1 is an unsubstituted or substituted alkyl or aryl radical, R.sub.2 is a hydroxyl group, lower alkoxy, alkylthio, alkylamino, dialkylamino or chlorine, X is halogen or is selected from the group consisting of --CF.sub.3, --NO.sub.2 or --CN, n is 0 to 3, and Y is selected from the group consisting of --NO.sub.2, --NH.sub.2, --OH, --CN, or is halogen. Preferred compounds are 2-nitro-5-(2'-chloro-4'-trifluoromethylphenoxy)phenylalkylphosphinic acids and lower alkyl esters thereof. The invention also relates to the production of the novel phosphinic acid derivatives, starting from a 3,4-dinitrodiphenyl ether and reaction with a O,O-dialkylalkyl- or -arylphosphonite as first step. The invention further relates to herbicidal and plant growth regulating compositions which contain one of these novel compounds as active component, and also to the use of these compounds and compositions for controlling weeds (also selectively), for inhibiting plant growth and desiccating parts of plants above the ground, as well as for totally destroying existing plant growth.
REFERENCES:
patent: 4322375 (1982-03-01), Maier et al.
Cadagan et al., "The Reaction of Triethyl Phosphite . . . ", Chem. Comm. 1966, 491-492.
Sieper, "Uber eine Bildungsueise . . . Nitrophenyl-Phosphons/a/ vre ester", Tetrah. Letters No. 21, 1987-1989 (1967).
Cadogan et al., "The Reactivity of Organophosphorous Compounds, Part XXV . . . ", J. Chem. Soc. 1969, 1314-1318.
Kasolapoff & Maier, Organophosphorus Compounds?, 226-227.
Ciba-Geigy Corporation
Rabin Frederick H.
Sutto Anton H.
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