Plant protecting and regulating compositions – Plant growth regulating compositions – Organic active compound containing
Patent
1996-08-15
1997-12-23
Dees, Jose G.
Plant protecting and regulating compositions
Plant growth regulating compositions
Organic active compound containing
504225, 504245, 544 582, 544173, 544175, 546 81, 546 86, C07D26536, C07D27916, C07D295104, C07D47102
Patent
active
057007616
DESCRIPTION:
BRIEF SUMMARY
BACKGROUND OF THE INVENTION
This invention comprises tricyclic imides, pyrazoles, and triazolones, and bicyclic ureas wherein one of the rings is a fused cyclopropane, and their agriculturally-suitable salts, for weed control in crops.
EP-A-493,323 discloses bicyclic imide herbicides, WO 93/15074 discloses bicyclic pyrazole herbicides, and U.S. Pat. No. 4,213,773 discloses bicyclic triazolone herbicides, but they lack the fused cyclopropane ring present in the compounds of this invention.
SUMMARY OF THE INVENTION
The compounds of this invention are compounds of Formulae I-IV: ##STR2## wherein Q is ##STR3## R.sup.1 is independently hydrogen; halogen or C.sub.1 -C.sub.3 alkyl; R.sup.2 is independently hydrogen; fluorine; chlorine; or bromine; OH; OR.sup.9 ; SH; S(O).sub.n R.sup.9 ; COR.sup.9 ; CO.sub.2 R.sup.9 ; C(O)SR.sup.9 ; C(O)NR.sup.11 R.sup.12 ; CHO; CR.sup.11 .dbd.NOR.sup.18 ; CH.dbd.CR.sup.19 CO.sub.2 R.sup.9 ; CH.sub.2 CHR.sup.19 CO.sub.2 R.sup.9 ; CO.sub.2 N.dbd.CR.sup.13 R.sup.14 ; NO.sub.2 ; CN; NHSO.sub.2 R.sup.15 ; NHSO.sub.2 NHR.sup.15 ; NR.sup.9 R.sup.20 ; NH.sub.2 or phenyl optionally substituted with R.sup.21 ; SCH.sub.3 ; OCHF.sub.2 ; halogen; CN or NO.sub.2 ; cyclopropyl; vinyl; C.sub.2 alkynyl; CN; C(O)R.sup.20 ; CO.sub.2 R.sup.20 ; C(O)NR.sup.20 R.sup.22 ; CR.sup.16 R.sup.17 CN; CR.sup.16 R.sup.17 C(O)R.sup.20 ; CR.sup.16 R.sup.17 CO.sub.2 R.sup.20 ; CR.sup.16 R.sup.17 C(O)NR.sup.20 R.sup.22 ; CHR.sup.16 OH; CHR.sup.16 OC(O)R.sup.20 or OCHR.sup.16 OC(O)NR.sup.20 R.sup.22 ; or when Q is Q-2, R.sup.6 and R.sup.7 can be taken together with the carbon to which they are attached to form C.dbd.O; -C.sub.6 alkoxyalkyl; C.sub.3 -C.sub.6 alkenyl; C.sub.3 -C.sub.6 alkynyl; C.sub.4 -C.sub.7 cycloalkyalkyl; ##STR4## R.sup.9 is C.sub.1 -C.sub.8 alkyl; C.sub.3 -C.sub.8 cycloalkyl; C.sub.3 -C.sub.8 alkenyl; C.sub.3 -C.sub.8 alkynyl; C.sub.1 -C.sub.8 haloalkyl; C.sub.2 -C.sub.8 alkoxyalkyl; C.sub.2 -C.sub.8 alkylthioalkyl; C.sub.2 -C.sub.8 alkylsulfinylalkyl; C.sub.2 -C.sub.8 alkylsulfonylalkyl; C.sub.4 -C.sub.8 alkoxyalkoxyalkyl; C.sub.4 -C.sub.8 cycloalkylalkyl; C.sub.6 -C.sub.8 cycloalkoxyalkyl; C.sub.4 -C.sub.8 alkenyloxyalkyl; C.sub.4 -C.sub.8 alkynyloxyalkyl; C.sub.3 -C.sub.8 haloalkoxyalkyl; C.sub.4 -C.sub.8 haloalkenyloxyalkyl; C.sub.4 -C.sub.8 haloalkynyloxyalkyl; C.sub.6 -C.sub.8 cycloalkylthioalkyl; C.sub.4 -C.sub.8 alkenylthioalkyl; C.sub.4 -C.sub.8 alkynylthioalkyl; C.sub.1 -C.sub.4 alkyl substituted with phenoxy or benzyloxy, each ring optionally substituted with halogen, C.sub.1 -C.sub.3 alkyl or C.sub.1 -C.sub.3 haloalkyl; C.sub.4 -C.sub.8 trialkylsilylalkyl; C.sub.3 -C.sub.8 cyanoalkyl; C.sub.3 -C.sub.8 halocycloalkyl; C.sub.3 -C.sub.8 haloalkenyl; C.sub.5 -C.sub.8 alkoxyalkenyl; C.sub.5 -C.sub.8 haloalkoxyalkenyl; C.sub.5 -C.sub.8 alkylthioalkenyl; C.sub.3 -C.sub.8 haloalkynyl; C.sub.5 -C.sub.8 alkoxyalkynyl; C.sub.5 -C.sub.8 haloalkoxyalkynyl; C.sub.5 -C.sub.8 alkylthioalkynyl; C.sub.2 -C.sub.8 alkylcarbonyl; benzyl optionally substituted with halogen, C.sub.1 -C.sub.3 alkyl or C.sub.1 -C.sub.3 haloalkyl; CHR.sup.16 COR.sup.10 ; CHR.sup.16 P(O)(OR.sup.10).sub.2 ; CHR.sup.16 P(S)(OR.sup.10).sub.2 ; P(O)(OR.sup.10).sub.2 ; P(S)(OR.sup.10).sub.2 ; CHR.sup.16 C(O)NR.sup.11 R.sup.12 ; CHR.sup.16 C(O)NH.sub.2 ; CHR.sup.16 CO.sub.2 R.sup.10 ; CO.sub.2 R.sup.10 ; SO.sub.2 R.sup.10 ; phenyl optionally substituted with R.sup.21 ; ##STR5## R.sup.10 is C.sub.1 -C.sub.6 alkyl; C.sub.1 -C.sub.6 haloalkyl; C.sub.3 -C.sub.6 alkenyl or C.sub.3 -C.sub.6 alkynyl; optionally substituted with halogen, C.sub.1 -C.sub.3 alkyl or C.sub.1 -C.sub.3 haloalkyl; or they are attached to form a piperidinyl, pyrrolidinyl or morpholinyl ring, each ring optionally substituted with C.sub.1 -C.sub.3 alkyl, phenyl or benzyl; or attached to form C.sub.3 -C.sub.8 cycloalkyl; -C.sub.6 alkynyl; halogen; or alkyl; SCH.sub.3 ; OCHF.sub.2 ; halogen; CN or NO.sub.2 ; and -C.sub.6 cycloalkyl; C.sub.3 -C.sub.6 halocycloalkyl; and phenyl optionally substituted with up to three substituents independently selected from the group
REFERENCES:
patent: 4213773 (1980-07-01), Wolf
patent: 5073186 (1991-12-01), Los
Dees Jos,e G.
Degussa - Aktiengesellschaft
E. I. Du Pont de Nemours and Company
Oswecki Jane C.
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