Hemihydrate type phosphoric acid process with crystal modifier

Chemistry of inorganic compounds – Treating mixture to obtain metal containing compound – Alkaline earth metal

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423266, 423320, C01B 2516, C01F 100, C01F 500, C22B 2620

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041407482

ABSTRACT:
Phosphate rock and sulfuric acid are reacted to produce phosphoric acid and calcium sulfate by means of the hemihydrate wet process. In this improved process, the calcium sulfate hemihydrate is crystallized from solution in the presence of an organic sulfonic acid or a derivative thereof. The organic sulfonic acid or its derivative improves the growth of the calcium sulfate hemihydrate crystals and thus improves the filtration rate of the slurry produced in this improved process.

REFERENCES:
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patent: 3192014 (1965-06-01), Leyshen et al.
patent: 3197280 (1965-07-01), Boyle et al.
patent: 3418077 (1968-12-01), Robinson
patent: 3522003 (1970-07-01), Lopker
patent: 3522004 (1970-07-01), Lopker
patent: 3594123 (1971-07-01), Encke et al.
patent: 3653827 (1972-04-01), Hey et al.
patent: 3796790 (1974-03-01), Sirianni et al.
Phosphoric Acid-Slack-1968-pp. 279 to 284 and 383 to 386.
Chemical Industries-vol. 64-5/49-"Chemical Antifoaming Agents", by Ross-pp. 757-759.

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