Heat-treated active carbons for use in denitration,...

Chemical apparatus and process disinfecting – deodorizing – preser – Chemical reactor – Waste gas purifier

Reexamination Certificate

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C422S169000, C422S170000

Reexamination Certificate

active

07465429

ABSTRACT:
This invention relates to a technique for removing nitrogen oxides (NOx) present in exhaust gases discharged from boilers and the like. When the temperature of the exhaust gas is 100° C. or below, a heat-treated active carbon produced by heat-treating a raw active carbon at 600 to 1,200° C. in a non-oxidizing atmosphere so as to remove oxygen-containing functional groups present at the surfaces thereof and thereby reduce the atomic surface oxygen/surface carbon ratio to 0.05 or less is preferably used. When the temperature of the exhaust gas exceeds 100° C., a heat-treated active carbon produced by heat-treating a raw active carbon at 600. to 1,200° C. in a non-oxidizing atmosphere and activating the surfaces thereof with sulfuric acid or nitric acid to impart oxidizing oxygen-containing functional groups thereto is preferably used.

REFERENCES:
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patent: 4256728 (1981-03-01), Nishino et al.
patent: 4831011 (1989-05-01), Oikawa et al.
patent: 4855116 (1989-08-01), Richter et al.
patent: 5172307 (1992-12-01), Tabuchi et al.
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patent: 5462908 (1995-10-01), Liang et al.
patent: 54064091 (1979-05-01), None
patent: 60/79176 (1994-03-01), None
patent: 9416806 (1994-08-01), None
Matsumura, ‘The Effects of Hydrophilic Structures of Active Carbons on the Adsorption of Benzene and Methanol Vapors’ in Carbon vol. 23 No. 3 pp. 263-271.

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