Stock material or miscellaneous articles – Sheet including cover or casing – Filled with gas other than air; or under vacuum
Patent
1997-04-25
2000-11-07
Thomas, Alexander S.
Stock material or miscellaneous articles
Sheet including cover or casing
Filled with gas other than air; or under vacuum
428 71, 428 76, B32B 106
Patent
active
061433896
DESCRIPTION:
BRIEF SUMMARY
BACKGROUND OF THE INVENTION
It is known that heat insulating bodies (vacuum panels) can be manufactured from a porous material and a gas-tight sheet which provides an all-round cladding, the "hollow space" formed by the porous material being evacuated. The porous material may consist either of an expanded bulk material, or of a rigid foamed material, however. The sheet usually consists of combinations of several layers, with different functions being performed by the different layers, such as a diffusion barrier to various gases and mechanical reinforcement.
Most commercially available vacuum panels have a core of inorganic bulk material, which is usually silicate-based.
EP-B-188 806 describes rigid foamed materials based on polyurethane (PUR) as a filler material for vacuum panels. The problem with this process is to achieve the requisite open cellularity by the precise selection of the formulation and by adhering to defined process parameters, since PUR rigid foamed materials are predominantly of closed cell structure. The outgassing of volatile constituents such as amines, foaming agents, and possibly monomers also, constitutes another problem when using PUR rigid foamed materials as a support material for vacuum panels.
On the other hand, one advantage of rigid PUR foamed materials compared with porous inorganic bulk materials is their accurate sizing as finished vacuum panels, as well as their dimensional stability.
Surprisingly, it has now been found that an excellent support material for vacuum panels can be produced in an economical manner by producing a porous bulk material by pulverising rigid foamed materials and processing this bulk material--similarly to porous silicate bulk materials--to form vacuum panels. In this connection rigid foamed materials are preferably used which arise in the recycling of valuable substances, and the PUR foamed material which arises on the recycling of refrigerators is particularly preferred in this respect.
SUMMARY OF THE INVENTION
The present invention thus relates to a heat insulating body consisting of inorganic porous material, and of hermetically sealed.
DETAILED DESCRIPTION OF THE INVENTION
According to the invention it is preferred that material which preferably originates from the process of recycling old refrigerators, freed from volatile constituents by heating at temperatures from 50 to 250.degree. C., preferably at 120 to 200.degree. C., optionally under low pressure, pre-pressed at pressures from 0.5 to 5 bar, preferably 1 to 3 bar, and polyethylene/polyvinyl alcohol sheet, is used as the cladding sheet,
All known sheets, e.g. combination sheets such as those which are also used in the production of commercially available vacuum panels, can be used for the vacuum panel produced according to the invention. The following may be cited as examples: a combination of polyethylene sheet with polyvinyl alcohol sheet or polyethylene sheet with aluminium sheet.
In principle, all rigid foamed plastic materials are suitable as foamed materials to be used according to the invention. Rigid polyurethane foamed materials are preferred. Even though the sheets used for vacuum panels are already highly impermeable to gases, nevertheless they do not constitute a gas or vapour barrier. In particular, water vapour which penetrates can have an adverse effect on the vacuum and thus on the heat insulating properties of the vacuum panel. In order to prevent this, vapour-absorbing substances, such as those based on silicate or alumina for example, can be used conjointly according to the invention in amounts from 10 to 90% by weight, preferably 20 to 50% by weight.
Comminution of the rigid foamed material can be effected according to the invention by milling, grinding or attrition; larger pieces of foamed material may also easily be crushed if necessary.
The fineness of the porosity can be adjusted according to the invention, firstly by the intensity of the milling process and secondly by the fineness of the cell structure of the foamed material to be pulverised.
Pre-pres
REFERENCES:
patent: 4492725 (1985-01-01), Ishihara et al.
patent: 4513041 (1985-04-01), Delluc
patent: 4668555 (1987-05-01), Uekado et al.
patent: 5273801 (1993-12-01), Barry et al.
patent: 5603887 (1997-02-01), Eschner
Dietrich Karl Werner
Thomas Heinz
Bayer Aktiengesellschaft
Cheung Noland J.
Gil Joseph C.
Thomas Alexander S.
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