Heat-induced formation of co-crystalline composition...

Radiation imagery chemistry: process – composition – or product th – Electric or magnetic imagery – e.g. – xerography,... – Radiation-sensitive composition or product

Reexamination Certificate

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C430S059400, C424S009362, C424S009610, C534S015000, C540S145000, C514S185000, C514S410000

Reexamination Certificate

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07008742

ABSTRACT:
A process for forming a cocrystalline mixture of titanyl phthalocyanine (TiOPc) and titanyl fluorophthalocyanine (TiOFPc) includes: dry milling a mixture of crude TiOPc and crude TiOFPc, thereby forming an amorphous pigment mixture of TiOPc and TiOFPc; and heating the amorphous pigment mixture at a temperature effective to form a cocrystalline composition comprising titanyl phthalocyanine (TiOPc) and titanyl fluorophthalocyanine (TiOFPc), the cocrystalline composition being characterized by an X-ray diffraction spectrum exhibiting intensity peaks at 7.2°, 12.9°, 16.3°, 22.3°, 24.6°, 26.2°, and 28.8° with respect to X-rays of Cu Kαat a wavelength of 1.54 1 Å of the Bragg angle 2θ.

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Paul Borsenberger, et al., “Organic Photoreceptors for Imaging Systems”, pp. 339-391.

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