Heat- and chemical-resistant acrylic short fibers without spinni

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428357, 428364, 1621574, 1621575, D02G 300

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active

054015766

ABSTRACT:
A new, pulp-like, acrylic short fiber having excellent heat- and chemical-resistance is provided. The fiber has a thickness distribution of 0.1 .mu.m to 50 .mu.m, a length distribution of 1 mm to 20 mm, and a thermal transition temperature (Tg) of above 200.degree. C. The fiber is produced by heating a mixture of polyacrylonitrile and water of about 5% to 100% by weight to temperatures above hydration-melting temperature under seal to an amorphous melt; cooling the resulting amorphous melt to temperatures between the melting and the solidifying temperatures of the melt to form a supercooled melt; extruding the resulting supercooled melt to give extrudates; heat-stabilizing the resulting extrudates at temperatures between 180.degree. C. and 300.degree. C. for 1 minute to 4 hours after drying and drawing; and cutting and beating the resulting heat-stabilized extrudates into an appropriate size.

REFERENCES:
patent: 2999788 (1961-09-01), Morgan
patent: 3486970 (1969-12-01), Troemel et al.
patent: 3770856 (1973-11-01), Ueki et al.
patent: 3984601 (1976-10-01), Blickenstaff
patent: 4140844 (1979-02-01), Lohwasser
patent: 4163770 (1979-08-01), Porosoff
patent: 5219501 (1993-06-01), Yoon et al.
B. G. Frushour, "A New Thermal Analytical Technique for Acrylic Polymers", Polymer Bulletin 4, pp. 305-314 (1981).

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