Specialized metallurgical processes – compositions for use therei – Compositions – Consolidated metal powder compositions
Patent
1991-04-24
1993-06-29
Walsh, Donald P.
Specialized metallurgical processes, compositions for use therei
Compositions
Consolidated metal powder compositions
75236, 75240, 75242, 75244, 75248, 419 38, 419 39, C22C 2904
Patent
active
052230201
DESCRIPTION:
BRIEF SUMMARY
The invention relates to a hard-metal body according to the introductory part of claim 1.
Such hard metals are already known, e.g. the European patent specification EP 0 195 965 A3 discloses a hard metal, which besides the hard-metal phase contains binder metal phase between 5 to 25% by weight, which is composed by 5 to 15% by weight chrome and the balance nickel, and whereby after sintering, the hard metal is treated for a period of 20 to 200 minutes in an atmosphere of inert gas, preferably an argon atmosphere, at a temperature of 1300.degree. to 1400.degree. C. and a pressure of 20 to 3000 bar.
The U.S. Pat. No. 3,215,510 discloses a hard-metal body consisting of 10 to 30% by mass of a chrome-nickel binder alloy, the balance made up by tungsten carbide, whereby the weight ratio of chrome to the binder metal ranges between 0.015 and 0.15. This hard-metal body is produced by pressing and sintering from powdery raw materials.
Finally the JP-A-56 136 952 presents a sintered hard-metal body on the basis of WC-Ni, which contains 3 to 30% Ni and 0.05 to 4.5% Cr, as well as 0.5 to 20% of at least one nitride of Ti, Zr, V, Nb. Further, in the German article by Kieffer and Benesowsky, in HARTMETALLE, 1965, pages 220, 221 and 228, a hard metal is described consisting of 90% by mass tungsten carbide, 8% by mass nickel and 2% by mass chrome. However, these in themselves corrosion-resistant hard metals have disadvantageously a very low strength and especially a very low ductility, so that their practical applications are limited.
From EP 0 028 620 B1 a further sintered hard alloy is known, which for the purpose of achieving good strength, ductility, as well as corrosion and oxidation resistance, consists of 55 by 95% by volume of hard materials with a minimum of 90% tungsten carbide and optionally further carbides, as well as 5 to 45% by volume single-phase binders with a minimum of 50% nickel, 2 to 25% chrome, 1 to 15% molybdenum and as a maximum for each 10% manganese, 5% aluminum, 5% silicon, 10% copper, 30% cobalt, 20% iron and 13% tungsten.
Finally, in EP 0 214 679 A1 a corrosion-resistant hard-metal alloy is proposed consisting of 31 to 84% by weight tungsten carbide, 15 to 60% by weight of one or several carbides of the group tantalum carbide, niobium carbide, zirconium carbide, titanium carbide, chrome carbide, molybdenum carbide,as well as 1 to 9% by weight of a binder alloy of nickel and/or cobalt with a 2 to 40% by weight chrome addition. This alloy is also supposed to have good mechanical strength characteristics and a high resistance to wear.
Experience has proven that the heretofore-known alloys are not satisfactory from the point of view of corrosion resistance.
It is therefore the object of the present invention to propose a hard-metal body having high mechanical strength as well as wear resistance, and in addition thereto, an improved resistance to corrosion.
This object is attained due to the hard-metal body defined in claim 1, consisting of tungsten carbide, 0.005 to 0.3% by mass TiN, chrome and nickel, whereby the proportion of TiN and binder metal phase together amounts to 5 to 25% by mass, and this proportion contains 5 to 15% by mass chrome and which is produced from powdery raw materials through pressing and sintering. The advantages of this alloy are an improved corrosion resistance, particularly in the medium sulfuric acid, and the simultaneous considerable reduction of abrasion wear. The good mechanical characteristics make possible a safe use of the alloy in chemical plants, as well materials exposed to extreme combustion temperatures.
According to a further embodiment of the invention, after sintering the hard-metal body is treated during 20 to 200 minutes in an atmosphere of inert gas, particularly argon atmosphere, at a temperature of 1300.degree. to 1400.degree. C. and at a pressure of 20 to 3000 bar. As a result of this treatment, the hard metal achieves a good strength and an excellent ductility, which can be explained by a high degree of densification of the hard-metal structure. Es
REFERENCES:
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Patent Abstract of Japan, vol. 6, No. 15 (C-089) 28 Jan. 1982.
Patent Abstract of Japan, vol. 9, No. 297 (M-432) 25 Nov. 85.
Dubno Herbert
Krupp Widia GmbH
Mai Ngoclan T.
Walsh Donald P.
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