Halogenated polycarboxycubanes

Chemistry: electrical and wave energy – Processes and products – Processes of treating materials by wave energy

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20415787, 20415789, 20415794, 560114, 560116, C07C 2300

Patent

active

053783336

ABSTRACT:
The disclosure describes photochemical synthesis of halogenated polycarboxycubanes from simple carboxycubanes and an oxalyl halide. It is possible to synthesize 6-Chloro-1,2,4,7-tetracarbomethoxycubane and 2-Chloro-1,3,5,7-tetracarbomethoxycubane. Photochemical synthesis of halogenated polycarboxycubanes from carboxy cubane and an oxalyl halide is reported.

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patent: 3551576 (1970-12-01), Loeffler
patent: 5214221 (1993-05-01), Bashir-Hashemi
patent: 5214222 (1993-05-01), Bashir-Hashemi
March, Jerry. Advanced Organic Chemistry: Reaction, Mechanism, and Struct 3rd edition, John Wiley & Sons, 1985, pp. 620-621.
Cubanes: Starting Materials for the New Century, Agnew Chem. Int. Engl. 1992, 31 1423.

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