Halogen-free blowing agents that include cycloaliphatic hydrocar

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Cellular products or processes of preparing a cellular...

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521114, 521130, 521131, C08G 1814

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active

053366964

ABSTRACT:
A halogen-free blowing agent is used to produce isocyanate-based polymeric foams. The blowing agent is an organic liquid which is free from halogens and contains a positive binary azeotrope having a minimum boiling temperature in the range of about 15.degree. C. to about 80.degree. C. at normal atmospheric pressure. Particularly preferred is a binary azeotrope of an alicyclic hydrocarbon such as cyclopentane or cyclohexane and methyl formate.
The halogen-free blowing agents contemplated herein provide the following advantages: no ozone depletion potential, no global warming potential, direct replacement in foam formulations for trichloromonofluoromethane (CFC-11), relatively higher blowing action, relatively lower foam density, relatively lower thermal conductivity, better compatibility, and relatively lower materials cost.

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