Half-metallocene catalyst compositions and their polymer...

Details Half-metallocene catalyst compositions and their polymer... Half-metallocene catalyst compositions and their polymer...

2011-02-08

2011-02-08

Lu, Caixia (Department: 1796)

Synthetic resins or natural rubbers -- part of the class 520 ser

Synthetic resins

Polymers from only ethylenic monomers or processes of...

C526S129000, C526S160000, C526S348000, C526S348200, C526S943000, C502S103000, C502S120000, C502S152000, C502S155000

Reexamination Certificate

active

07884165

ABSTRACT:
The present invention provides polymerization catalyst compositions employing half-metallocene compounds with a heteroatom-containing ligand bound to the transition metal. Methods for making these hybrid metallocene compounds and for using such compounds in catalyst compositions for the polymerization and copolymerization of olefins are also provided.

REFERENCES:
patent: 3242099 (1966-03-01), Manyik
patent: 3248179 (1966-04-01), Norwood
patent: 4060480 (1977-11-01), Reed
patent: 4452910 (1984-06-01), Hopkins
patent: 4501885 (1985-02-01), Sherk et al.
patent: 4588790 (1986-05-01), Jenkins, III et al.
patent: 4794096 (1988-12-01), Ewen
patent: 4808561 (1989-02-01), Welborn
patent: 4871705 (1989-10-01), Hoel
patent: 4939217 (1990-07-01), Stickler
patent: 5332706 (1994-07-01), Nowlin et al.
patent: 5352749 (1994-10-01), DeChellis et al.
patent: 5376611 (1994-12-01), Shveima
patent: 5436304 (1995-07-01), Griffin et al.
patent: 5455314 (1995-10-01), Burns et al.
patent: 5539076 (1996-07-01), Nowlin et al.
patent: 5556821 (1996-09-01), Aida et al.
patent: 5565175 (1996-10-01), Hottovy et al.
patent: 5575979 (1996-11-01), Hanson
patent: 5576259 (1996-11-01), Hasegawa
patent: 5635573 (1997-06-01), Harrington et al.
patent: 5698651 (1997-12-01), Kawasaki et al.
patent: 5747405 (1998-05-01), Little et al.
patent: 5807938 (1998-09-01), Kaneko
patent: 5861352 (1999-01-01), Gila et al.
patent: 5906955 (1999-05-01), Hamura
patent: 5919983 (1999-07-01), Rosen
patent: 5942459 (1999-08-01), Sugano et al.
patent: 5962362 (1999-10-01), Wasserman et al.
patent: 6107230 (2000-08-01), McDaniel et al.
patent: 6127302 (2000-10-01), Wasserman
patent: 6159889 (2000-12-01), Wasserman
patent: 6165929 (2000-12-01), McDaniel et al.
patent: 6239235 (2001-05-01), Hottovy et al.
patent: 6242622 (2001-06-01), Oda et al.
patent: 6262191 (2001-07-01), Hottovy et al.
patent: 6294494 (2001-09-01), McDaniel et al.
patent: 6300271 (2001-10-01), McDaniel et al.
patent: 6316553 (2001-11-01), McDaniel et al.
patent: 6340652 (2002-01-01), Sugano et al.
patent: 6355594 (2002-03-01), McDaniel et al.
patent: 6376415 (2002-04-01), McDaniel et al.
patent: 6388017 (2002-05-01), McDaniel et al.
patent: 6391816 (2002-05-01), McDaniel et al.
patent: 6395666 (2002-05-01), McDaniel et al.
patent: 6410657 (2002-06-01), Ko et al.
patent: 6469117 (2002-10-01), Kuang et al.
patent: 6524987 (2003-02-01), Collins et al.
patent: 6528448 (2003-03-01), Jensen et al.
patent: 6531550 (2003-03-01), McDaniel et al.
patent: 6548441 (2003-04-01), McDaniel et al.
patent: 6548442 (2003-04-01), McDaniel et al.
patent: 6576583 (2003-06-01), McDaniel et al.
patent: 6613712 (2003-09-01), McDaniel et al.
patent: 6632894 (2003-10-01), McDaniel et al.
patent: 6667274 (2003-12-01), Hawley et al.
patent: 6750302 (2004-06-01), McDaniel et al.
patent: 6825369 (2004-11-01), Stevens et al.
patent: 6833415 (2004-12-01), Kendrick et al.
patent: 6982306 (2006-01-01), Martin et al.
patent: 7226886 (2007-06-01), Jayaratne et al.
patent: 7294599 (2007-11-01), Jensen et al.
patent: 7390764 (2008-06-01), McDaniel et al.
patent: 7417097 (2008-08-01), Yu et al.
patent: 2005/0113243 (2005-05-01), Thorn et al.
patent: 0 989 139 (2000-03-01), None
patent: 1 102 795 (2001-05-01), None
patent: WO 2004/018489 (2004-03-01), None
Search Report for International Application No. PCT/US2009/004047, mailed Dec. 10, 2009.
Arevalo, Silvia, et al.Ethylene polymerization behavior of monometallic complexes and metallodendrimers based on cyclopentadienyl-aryloxy titanium units, Journal of Organometallic Chemistry 690 (2005) 4620-4627.
Antinolo, A., et al.Synthesis of Zirconium(IV)Monocyclopentadienyl-Aryloxy Complexes and Their Use in Catalytic Ethylene Polymerization. X-ray Structure of(η5-C5Me5)Zr{2,6-OC6H3(CH3)2}3,Organometallics2000, 19, 2837-2843.
Thom, Matthew G., et al.,Synthesis, Characterization, and One-Election Reduction of Mixed-Cyclopentadienyl/Aryloxide Titanium Dichlorides, Organometallics 2000, 19, 5636-5642.
Arevalo, Silvia, et al.,Synthesls of Aryloxo Cyclopentadienyl Group 4 Metal-Containing Dendrimers, Organometallics 2003, 22, 5109-5113.
Nicholas, et al., “Synthesis, Spectroscopy, and Catalytic Properties of Cationic Organozirconium Adsorbates on “Super Acidic” Sulfated Alumina. “Single-Site” Heterogeneous Catalysts with Virtually 100% Active Sites,” J. Am. Chem. Society, (2003) 125, pp. 4325-4331.
Nicholas, et al. “Zirconium Hydrocarbyl Chemisorption on Sulfated Metal Oxides: New Supports, Chemisorption Pathways, and Implications for Catalysis,” Langmuir, (2004) 20, pp. 9456-9462.
Byun et al., “Effect of Cyclopentadienyl and Anionic Ancillary Ligand in Syndiospecific Styrene Polymerization Catalyzed by Nonbridged Half-Titanocenes Containing Aryloxo, Amide, and Anilide Ligands: Cocatalyst Systems,” Macromolecules 2004, vol. 37, pp. 5520-5530.
Fenwick et al., “Formation of Neutral and Cationic Methyl Derivatives of Titanium Containing Cyclopentadienyl and Aryloxide Ancillary Ligation,” Organometallics 2004, vol. 23, pp. 2146-2156.
Itagaki et al., “Ethylene polymerization and ethylene/1-octene copolymerization using group 4 half-metallocenes containing aryloxo ligands, Cp*MC12(Oar)-MAO catalyst systems,” Journal of Molecular Catalysis A: Chemical 2009, vol. 303, pp. 102-109.
Nomura et al., “Effect of aryloxide ligand in 1-hexene, styrene polymerization catalyzed by nonbridged half-titanocenes of the type . . . ,” Journal of Molecular Catalysis A: Chemical 2006, vol. 254, pp. 197-205.
Manz et al., “Supporting Information Part 1: Experimental Details, Kinetic Analysis, and Model Optimization,” J. Am. Chem. Soc. 2007, vol. 129, pp. 3776-3777.
Nomura et al., “Ethylene/α-olefin copolymerization by various nonbridged (cyclopentadienyl)(aryloxy)titanium(IV) complexes—MAO catalyst system,” Journal of Molecular Catalysis A: Chemical 2001, vol. 174, pp. 127-140.
Phomphrai et al., “Diverse Pathways of Activation and Deactivation of Half-Sandwich Aryloxide Titanium Polymerization Catalysts,” Organometallic 2006, vol. 25, pp. 214-220.
Nomura et al., “Syndiospecific Styrene Polymerization and Efficient Ethylene/Styrene Copolymerization Catalyzed by (Cyclopentadienyl)(aryloxy)titanium(IV) complexes—MAO System,” Macromolecules 2000, vol. 33, pp. 8122-8124.
Scholz et al., “Benzylverbindungen elektronenarmer Übergangsmetalle . . . ,” Journal of Organometallic Chemistry 1993, vol. 443, pp. 93-99.
Thorn et al., “Synthesis, structure and molecular dynamics of η2—iminoacyl . . . ,” Journal of the Chemical Society, Dalton Transactions 2002, vol. 17, pp. 3398-3405.
Pinnavaia, “Intercalated Clay Catalysts,” Science 1983, vol. 220, No. 4595, pp. 365-371.
Thomas et al., “Sheet Silicate Intercalates: New Agents for Unusual Chemical Conversions*,” Intercalation Chemistry (S. Whittington) 1972, Ch.3, pp. 55-99.
Li, et al., Coordination Copolymerization of Severely Encumbered Isoalkenes with Ethylene: Enhanced Enchainment Mediated by Binuclear Catalysts and Cocatalysts, JACS Articles, 2005, 127, 14756-14768.
Hieber et al., “Some correlations involving the shear viscosity of polystyrene melts,” Rheologica Acta 28 (1989), pp. 321-332.
Hieber et al., “Shear-Rate-Dependence Modeling of Polymer Melt Viscosity,” Polymer Engineering and Science 1992, vol. 32, No. 14, pp. 931-938.
Bird et al., “Dynamics of Polymeric Liquids,” vol. 1, Fluid Mechanics, 2nd Edition, John Wiley & Sons (1987), 3 pages.

Affiliated with

Also associated with

Rating

Half-metallocene catalyst compositions and their polymer... does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Half-metallocene catalyst compositions and their polymer..., we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Half-metallocene catalyst compositions and their polymer... will most certainly appreciate the feedback.

Rate now

Comments { 0 }

Profile ID: LFUS-PAI-O-2618699